Bonds and Electrons in Organic Compounds

 
In-class Board practice counting
bonds and electrons for organics
bond energies , bond lengths and bond order’s role in food
(see also p 91 table 3.1 of text)
 
Bond
C-C
C=C
C
C
C-H
 
Bond order
1
2
3
1
 
Bond energy 
kJ/mol
376
611
835
470
 
Bond length 
pm
154
133
120
109
Saturated => all C-C
 no C=C or C
C
Unsaturated => C-C and
some C=C and C
C
 
sushi
 
Hard fats (Crisco )
 
Oils (Olive oil)
 
WHY BAD ???
The straight story on why `saturated’ is bad…..
 
1 C-C bond * 376 kJ
 
Bond
C-C
C=C
C
C
C-H
 
Bond energy 
kJ/mol
376
611
835
470
Bond energy
contributions
 
6 C-H bonds* 470 kJ
 
1 C=C bond*611 kJ
 
4 C-H bonds*470 kJ
 
1 C
C bond*835 kJ
 
2 C-H bonds*470 kJ
Total bond
energy
 
3196 kJ
 
2490 kJ
 
1775 kJ
 
Saturated
 
Unsaturated
 
poly
unsaturated
 
100% (ref)
relative energy
comparison”
 
78%
 
56%
 
MOST
PROCESSED
FOODS ARE
SATURATED FAT
PRODUCTS
Tongue in `cheek’….but not far from the mark….
???
 
Can I have four bonds
between C ? Five bonds
? ½ bonds ?
 
Can C=H exist ? C
H ??
 
Do I use all or just
some of the electrons
of participating atoms
in bonds?
Doc’s annoying
questions habit
rears it ugly
head….
Some MORE annoying Doc questions
 
(see also: pp 100-106)
1.
What’s `shared’ in a shared electron bond  ?
 
2.
What rules govern the number of bonds to the
elements and how do we use these rules to
build organic (and other non-ionic) compounds
?
 
3.
How do we `read’ organic compound formulas
and deduce their bond and electron
arrangements 
?
The `Inventor’ of the
 Shared Electron 
P
air 
B
ond
Gilbert
 Newton 
Lewis
 
The House that Lewis
Built:
 
Lewis Hall of
Chemistry
UC Berkeley
 
As an
undergrad
…young
Doc Fong sits in
here staring every
day at…
1.
What’s `shared’ in a shared electron bond  ?
 
That’s easy,
maggot…..”
 
Uncle
`Gil’ sez:
Gilbert
 
Newton 
Lewis: (Uncle Gil)
Am
er
i
can
 Ch
em
ist
1.
What’s `shared’ in a shared electron bond  ?
Answer:
Just the outer shell or `valence’ electrons of
bonding atoms.
 
:
S
:
 
..
 
The main
`visual ’:
Lewis dots
1          2                                                                                      3        4      5       6
Inert gas core electrons for S
‘Valence’ vs `Core’ electrons
Valence
 shell or outer shell of S
How many
total electrons
does 
S 
have 
?
16
How many
 valence
electrons does 
S
have ?
6
How many `core’
electrons does 
S
 have ?
10
(Ne)
 
:
S
:
.
Dot picture shows only 
valence
electrons
 
..
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Explore the world of organic chemistry by delving into the concepts of bonds, electrons, and their roles in determining properties of organic compounds. Discover why saturated fats are considered unhealthy, learn about bond energies, lengths, and orders, and unravel the mysteries of organic compound formulas and electron arrangements.

  • Organic chemistry
  • Bond energies
  • Electrons
  • Saturated fats
  • Chemistry education

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  1. In-class Board practice counting bonds and electrons for organics

  2. bond energies , bond lengths and bond orders role in food (see also p 91 table 3.1 of text) Bond C-C C=C C C C-H Saturated => all C-C no C=C or C C Bond order 1 2 3 1 Bond energy kJ/mol 376 611 835 470 Bond length pm 154 133 120 109 Unsaturated => C-C and some C=C and C C Oils (Olive oil) Hard fats (Crisco ) sushi WHY BAD ???

  3. The straight story on why `saturated is bad.. Bond C-C C=C C C C-H Bond energy kJ/mol 376 611 835 470 H H H H H C C H C C H C C H H H poly unsaturated H H Saturated Unsaturated Bond energy contributions 1 C C bond*835 kJ 2 C-H bonds*470 kJ 1 C-C bond * 376 kJ 1 C=C bond*611 kJ 4 C-H bonds*470 kJ 6 C-H bonds* 470 kJ Total bond energy 3196 kJ 2490 kJ 1775 kJ relative energy comparison 100% (ref) 78% 56%

  4. MOST PROCESSED FOODS ARE SATURATED FAT PRODUCTS

  5. Tongue in `cheek.but not far from the mark.

  6. Can I have four bonds between C ? Five bonds ? bonds ? ??? Can C=H exist ? C H ?? Doc s annoying questions habit rears it ugly head . Do I use all or just some of the electrons of participating atoms in bonds?

  7. Some MORE annoying Doc questions (see also: pp 100-106) 1.What s `shared in a shared electron bond ? 2.What rules govern the number of bonds to the elements and how do we use these rules to build organic (and other non-ionic) compounds ? 3.How do we `read organic compound formulas and deduce their bond and electron arrangements ?

  8. The `Inventor of the Shared Electron Pair Bond Gilbert Newton Lewis As an undergrad young Doc Fong sits in here staring every day at The House that Lewis Built:Lewis Hall of Chemistry UC Berkeley

  9. 1.Whats `shared in a shared electron bond ? Uncle `Gil sez: That s easy, maggot .. Gilbert Newton Lewis: (Uncle Gil) American Chemist

  10. 1.Whats `shared in a shared electron bond ? Answer: Just the outer shell or `valence electrons of bonding atoms. .. The main `visual : Lewis dots :S:

  11. Valence vs `Core electrons How many `core electrons does S have ? 10 (Ne) Inert gas core electrons for S How many total electrons does S have ?16 How many valence electrons does S have ? .. Valence shell or outer shell of S 6 1 2 3 4 5 6 :S: . Dot picture shows only valence electrons

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