Practice Making Ketones and Aldehydes: Organic Chemistry Drills
"Enhance your knowledge of ketones, aldehydes, and related reactions through comprehensive organic chemistry drills. Explore reactions like PCC, OH, K2Cr2O7, and more to sharpen your understanding. Dive into core concepts with keto-enol tautomerism, hydroboration, Friedel-Crafts acylation, and Corey-House reactions. Take on side exercises on carboxylic acids and acid chlorides for a well-rounded learning experience."
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Presentation Transcript
Drill & Practice Making Ketones and Aldehydes pcc OH O K2Cr2O7 H2SO4 OH O OH K2Cr2O7 H2SO4 OH O
Drill & Practice Making Ketones and Aldehydes (continued) O3/in freon Zn/H+ O 2 H HgSO4/ H2SO4 + H2 O O Hint: keto-enol and Markovnikoff H2O2 /OH- BH3/neat or in THF H.C. Brown s 2 step hydroboration/oxidation O Name of reaction ? H
Drill & Practice Making Ketones and Aldehydes (continued) O3/in freon Zn/H+ 2 O H O Cl2/neat H2O O Cl O + Al Name of this reaction ?? Cl Cl Cl Friedel-Crafts Acylation
Drill & Practice Making Ketones and Aldehydes (continued) Cu Li O Cl O Name of this reaction ? Corey-House reaction Cl Li(Al-tBuO)3 In ether or neat H O O SOCl2/pyridine or PCl3 neat H O Cl O O
Drill & Practice Making Ketones and Aldehydes (continued) Side exercises on making carboxylic acids and acid chlorides KMnO4 O OH heat OH Mg/dry ether CO2(g) H+/H2O OH C Cl O NaCN in ethanol H+(acid) OH C O Cl or base, then acid
Side exercises on making carboxylic acids and acid chlorides (cont.) Hot KMnO4 or K2Cr2O7 In H2SO4 H O O In a solvent SOCl2 Cl OH R C R C O O PCl3(g) neat
