Understanding Chemical Hair Relaxers: Thio vs. Hydroxide

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Chemical hair relaxers like Thio and Hydroxide are common methods for straightening extremely curly hair. Thio relaxers use Ammonium Thioglycolate to break disulfide bonds, while Hydroxide relaxers contain strong alkalis that swell hair fibers. The process involves lanthionization and neutralization to maintain hair health post-treatment.


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  1. Chemical Texture Services Part 2 Chemical Hair Relaxers

  2. Chemical Hair Relaxing - the process of rearranging the basic structure of extremely curly hair into a straight form

  3. Extremely curly hair - grows in long, twisted spirals or coils - cross-sections are highly elliptical - vary in shape and thickness along their lengths

  4. The two most common types of chemical hair relaxers are thio (ATG) & hydroxide

  5. Thio Relaxers

  6. Ammonium Thioglycolate (ATG) Same reducing agent used in Permanent Waving but Usually has a pH above 10 Higher concentration of ATG thicker, with a higher viscosity break disulfide bonds and soften hair

  7. The neutralizer used with thio relaxers is an oxidizing agent usually hydrogen peroxide.

  8. Hydroxide Relaxers

  9. Hydroxide Ions active ingredient in all hydroxide relaxer very strong alkalis swell the hair up to twice its normal diameter average pH of hydroxide relaxers is over 13.0

  10. Lanthionization: process where hydroxide relaxers remove one atom of sulfur from a disulfide bond converting it to a lanthionine bond

  11. Neutralization does not involve oxidation neutralizes the alkaline residues left in the hair by the relaxer must apply an acid-balanced shampoo or a normalizing lotion lowers the pH of the hair & scalp

  12. Types of Hydroxide Relaxers

  13. Metal Hydroxide Relaxers A. One solution No mixing B. ionic compounds formed by a metal (sodium (Na), potassium (K), & lithium (Li)) which is combined with 1) oxygen (O) 2) hydrogen (H)

  14. Metal Hydroxide Relaxers A. Sodium hydroxide (NaOH) a) most common b) Aka - Lye Relaxers B. Potassium hydroxide (KOH) a) Aka No-Lye Relaxers C. Lithium hydroxide (LiOH) 1) Aka - No-lye relaxer

  15. Guanidine Hydroxide Relaxers advertised and sold as no lye relaxers contain two components that must be mixed immediately prior to use

  16. Low-pH Relaxers sulfites and bisulfites are sometimes used the most commonly used are ammonium sulfite and ammonium bisulfate

  17. Hydroxide Relaxers Base and No-Base Relaxers 1.)Base Relaxer base cream AKA protective base cream applied to the skin and scalp during hair relaxing 2.)No-base formula base cream AKA protective base cream applied to the hairline during hair relaxing

  18. Base Relaxers require the application of a protective base cream to the entire scalp prior to the application of the relaxer

  19. No-Base Relaxers does not require the application of a protective base cream contains a protective base cream designed to melt at body temperature

  20. Relaxer strengths Determined by the concentration of hydroxide ions Most chemical hair relaxers are available in three strengths: Mild Regular Super

  21. Thermal Ionic Reconstructors first manufactured and marketed in Asia consist of a thio relaxer with a double hot blow-dry and a double hot press with flat irons

  22. Soft Curl Permanents (Curl Re-forming) - do not STRAIGHTEN the hair - they make the existing curl larger and looser - AKA Jheri curl or simply a curl - actually two services

  23. Soft Curl Permanent Procedure 1. hair must be relaxed with a thio relaxer 2. Wrap hair on proper tools 3. process with a second thio solution 4. Always follow manufacturer s directions

  24. Keratin Based Straightening Treatments

  25. Keratin Based Straightening Treatments AKA Brazillian keratin treatments

  26. Hydroxide Relaxer Procedures

  27. Hydroxide Relaxer Procedures Virgin relaxer application used for hair that has not had previous chemical texture services Retouch relaxer application used for hair that has had previous chemical texture services

  28. Hydroxide Relaxer Procedures Normalizing Lotions used after rinsing out the relaxer and prior to shampooing conditioners with an acidic pH condition the hair and restore the natural pH prior to shampooing

  29. Strand Tests Done during processing helps determine when the hair is sufficiently relaxed AKA Thumb print If the hair pops up/follows your finger it is NOT finished processing

  30. Thio Relaxer Procedures

  31. Thio Relaxer Procedures application steps for thio relaxers are the same as those for hydroxide relaxer the neutralization procedure is different

  32. Safety Precautions for Hair Relaxing 1)Perform a thorough hair analysis and client consultation prior to the service 2)Examine the scalp for abrasions & do not proceed if redness, swelling, or skin lesions are present 3)Keep accurate and detailed client records of the services performed and the results

  33. 4)Have the client sign a release statement that indicated that the client understands the possible risks involved 5)Do not apply a hydroxide relaxer on hair that has been previously treated with a thio relaxer 6)Do not apply a thio relaxer on hair that has been previously treated with a hydroxide relaxer 7)Do not chemically relax hair that has been treated with a metallic dye

  34. 8)application of a hydroxide relaxer 9)Do not relax overly damaged hair 10)Do not shampoo the client prior to the The client s hair and scalp must be completely dry and free from perspiration prior to the application of a hydroxide relaxer 11)Apply a protective base cream to avoid scalp irritation 12)Wear gloves during the relaxer application

  35. 13)Protect the clients eyes 14)If any solution accidentally gets into the client s eye, flush the eye immediately with cool water and refer the client to a doctor 15)Do not allow chemical relaxers to accidentally come into contact with the client s ears, scalp, or skin 16)Perform periodic strand tests to see how fast the natural curls are being removed Avoid scratching the scalp with your comb or nails

  36. 17)Do not allow the application of a relaxer retouch to overlap onto previously relaxed hair 18)Never use a strong relaxer on fine or damaged hair, it may cause breakage 19)Do not attempt to remove more than 80% of the natural curl 20)Thoroughly rinse the chemical relaxer from the hair

  37. 21)Use a normalizing lotion to restore the hair and scalp to their normal acidic pH 22)Use a neutralizing shampoo with a color indicator to guarantee that the hair/scalp have been restored to their normal acidic pH 23)Use a conditioner and wide-tooth comb to eliminate excessive stretching when combing out tangles 24)Do not use hot irons or excessive heat on chemically relaxed hair

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