Macronutrients: Carbohydrates, Sugar, Proteins, Fats

 
Nutrition and Health
 
Macronutrients
 
Topics
 
Carbohydrates
Sugar
Starch
Cellulose
Proteins
Fats and Oils
Saturated fatty acids
Unsaturated fatty acids
Cholesterol
 
 
 
2
 
CARBOHYDRATES
 
 
3
 
Functions of Carbohydrates
 
Carbohydrate is an energy-giving nutrient
It provides energy for:
keeping the body warm
the body organs to work properly, e.g. breathing,
digesting
daily activities (e.g. sitting, walking) and other
physical activities (e.g. swimming, playing ball
games)
 
4
 
Types of Carbohydrates
 
There are three types of carbohydrates
Sugar
Starch
Cellulose
 
5
 
Sugar
 
What is sugar?
Sugar is a quick source of energy
It is an “empty energy food”, because it only
provides energy with no other nutrients
Sugar on food labels may appear as sucrose,
glucose / dextrose, fructose, maltose, lactose,
corn syrup, honey, and molasses
 
6
 
Sugar
 
Sources of sugar
Sugar is present in fruits, vegetables and milk
The sugar used everyday is mainly processed
from sugar cane or sugar beet
 
7
 
Sugar
 
Uses of sugar
Sugar is often added to processed foods
“Hidden sugar” is a component of processed
food that cannot be seen
 
8
 
Sugar
 
Sugar is the main cause of tooth decay
Excess sugar will be stored inside body as fat,
the result can be overweight
 
9
 
Starch
 
What is starch?
It consists of a large number of glucose units
joined together
The most common carbohydrate in the human
diet
Starch is contained in many staple foods
Starchy foods are good sources of energy
 
10
 
Starch
 
Sources of starch
Starch is stored in many plants
Foods that are rich in starch:
 
11
 
Starch
 
Dietary requirement
For an average adult, starch and sugar should
form about 50-60% of the daily energy
requirement
 
12
 
Dietary Requirement
 
13
 
Dietary Requirement
 
14
 
Dietary Requirement
 
Example:
 
If carbohydrate forms 55% of
daily energy requirement, how
much carbohydrate should a
person eat in one day?
 
(Assume the daily energy
requirement for this person is
1,800 kcal.)
 
Answer:
 
Energy originates from
carbohydrate:
1,800 kcal x 55%
= 990 kcal
 
Amount of carbohydrate to be
eaten per day:
990 kcal ÷ 3.75 kcal/gram
= 264 gram
 
15
 
Starch
 
Excess starch will be stored inside body as fat,
the result can be overweight
 
16
 
Cellulose
 
What is cellulose?
Cellulose is found in the wall of plant cells
It is the main source of dietary fibre
Dietary fibre helps to remove body waste
It prevents constipation and other intestinal
problems
 
17
 
Cellulose
 
18
 
Structure of Vegetables / Fruits
 
Cell wall, contains
cellulose, hemicellulose,
pectic substances, and
lignin
 
Plasma membrane
 
Ribosomes
 
Vacuole, holds water
and provides crispy
texture to vegetables
and fruits
 
Mitochondria
 
Chloroplast
 
Nucleus
 
Endoplasmic
reticulum
 
Cellulose
 
Sources of cellulose
Foods that are rich in cellulose: plant food like
whole grain wheat, oat, legumes, cabbage,
cauliflower, choy sum, berries, apples, etc.
Foods that do not contain cellulose: animal
food like pork, beef, fish, etc.
 
19
 
Cellulose
 
Dietary requirement
Reference value of dietary fibre: not less than
25g per day
Department of Health promotes “2 plus 3 a
day” in order to improve health and reduce
risks of chronic diseases
 
20
 
Source: Centre for Health Protection, Department of Health
 
Cellulose
 
One serving of fruit is approximately defined as:
2 pieces of small-sized fruits (such as plum, kiwifruit)
1 piece of medium-sized fruit (such as orange, apple)
½ piece of large-sized fruit (such as banana, grapefruit, star fruit)
½ bowl of fruit cuts (such as watermelon, cantaloupe, honeydew
melon)
½ bowl of mini-sized fruit (such as grapes, lychees, cherries,
strawberries)
1 tablespoon of dried fruits without added sugar or salt (such as
raisin, pitted prune)
¾ cup of pure fruit juice without added sugar (such as fresh orange
juice with pulp)
 
Remark: 1 cup = 240 ml
1 bowl = 250-300 ml
 
21
 
Source: Centre for Health Protection, Department of Health
 
Cellulose
 
One serving of vegetables is approximately defined as:
1 bowl of raw leafy vegetables (e.g. lettuce, purple cabbage)
½ bowl of cooked vegetables, sprouts, gourds, beans or
mushrooms (e.g. Chinese flowering cabbage, Chinese kale,
spinach, white cabbage, bean sprouts, eggplant, carrot,
snow pea, Enokitake mushroom)
¾ cup of fresh vegetable juice* without added sugar (e.g.
fresh tomato juice)
 
Remark: 1 cup = 240 ml
1 bowl = 250-300 ml
 
22
 
Source: Centre for Food Safety, Department of Health
 
PROTEINS
 
 
23
 
Functions of Proteins
 
For body growth
Repair and replace damaged cells
Provide energy
 
24
 
What is Protein?
 
Proteins are made up of amino acids
The human body needs 20 types of amino
acids to build all the proteins needed
nine of them are essential amino acids, i.e. cannot
be made by the body
the rest are non-essential amino acids
 
25
 
Types of Protein?
 
There are two types of protein:
High biological value (HBV) proteins
found in most animal proteins
contain a good amount of all the essential amino acids
Low biological value (LBV) proteins
found in most plant proteins
does not supply all the essential amino acids
 
 
26
 
Sources of Proteins
 
High biological value proteins
 
Meat
Poultry
Fish
Milk and dairy products
Egg
Bean curd
Soya bean is the only plant
food which provides HBV
proteins
 
Low biological value proteins
 
Rice
Bread
Almonds
Mung beans
Red beans
Cashew
Green peas
Gluten
Dried mushrooms
 
27
 
Improving the Protein Quality
of a Meal
 
When eating proteins from two different plant
sources, the amino acids in one food can
supplement the amino acids lacking in the
other food
In eating a plant protein food with an animal
protein food, the biological value of the
protein mixture in the meal is also improved
 
28
 
Improving the Protein Quality of a
Meal
 
Examples of
supplementing amino
acids with two different
foods
 
29
 
Proteins
 
Inadequate intake of protein
affect growth in children, slow down or even stop
growing
not common in adults, since most foods contain
proteins
Excessive intake of protein
excessive protein will be turned into energy and
stored in our body as fat
 
30
 
FATS AND OILS
 
 
31
 
Functions of Fats and Oils
 
Fat stores heat, which can be used as energy when
necessary. The layer of fat directly beneath our skin
also serves as a kind of insulation, which helps
maintain our body temperature.
Most fats are found in adipose tissues, which surround
and protect our body's internal organs.
Fat serves as a medium for transporting and absorbing
fat-soluble vitamins such as vitamins A, D, E and K.
Fat is an essential ingredient in the production of
cholesterol, bile acid, and certain hormones.
Fat ensures the proper functioning of our nervous
system and our skin.
 
32
 
Source: Centre for Health Protection, Department of Health
 
What are Fats and Oils?
 
Fat is a nutrient yielding high amount of
energy
The amount of energy provided by fat doubles
the amount of energy provided by
carbohydrates or protein of the same weight
People enjoy fats and oils in the diet due to its
flavour, mouthfeel, palatability, texture and
aroma
 
33
 
What 
are
 Fats and Oils?
 
Lipids are sometimes used as a synonym for fats
Lipids comprise a group of naturally occurring
molecules that includes fats, sterols, fat-soluble
vitamins, monoglycerides, diglycerides
,
triglycerides, and phospholipids
Two origins: plant and animal
Both fats and oils belong to lipids
“Fat” - solid at room temperature
“Oil” - liquid at room temperature
They are chemically similar, but differ in physical state
 
34
 
Types of Fats and Oils Based on Origin
 
35
 
Types of Fats and Oils Based on Origin
 
36
 
Types of Fats and Oils
 
37
 
Some fats are visible, some fats are invisible
 
Fats and Oils
 
Inadequate intake of fats and oils
not common in developed countries
can be seen occasionally in developing countries, may
hinder absorption of fat soluble vitamins, such as
vitamin A, hence causing night blindness
Excessive intake of fats and oils
excess fat will be stored in our body, and causing
overweight and obesity
individuals can have higher risk in developing chronic
diseases like coronary heart disease,
hypercholesterolaemia (high blood cholesterol), etc.
 
38
 
Structure and Composition of
Fats and Oils
 
Glycerides
Glycerides contain a glycerol molecule backbone joined
to one or more fatty acid molecules
There are monoglycerides, diglycerides, and
triglycerides
A monoglyceride contains glycerol esterified to one
fatty acid molecule
Fats and oils are triglycerides, the major constituent of
lipids
More than 95% of fatty substance in food is
triglycerides
 
39
 
Structure and Composition of
Fats and Oils
 
40
 
Glycerol
 
Three
fatty acid
chains
A triglyceride
 
One fatty
acid
chain
A monoglyceride
 
Structure and Composition of
Fats and Oils
 
Fatty acids
Fatty acids are long hydrocarbon chains with a methyl group (CH
3
)
at one end of the chain and a carboxylic acid group (COOH) at the
other
Most natural fatty acids contain from 4 to 24 carbon atoms and
most contain an even number of carbon atoms in the chain
Animal fats typically have 18 carbons in the fatty acid chain
These long chains are made of various fatty acids, such as saturated
fatty acid, monounsaturated fatty acid and polyunsaturated fatty
acid
 
41
Example of a saturated fatty acid
 
Sources of Fatty Acids
 
42
 
Sources of Fatty Acids
 
43
 
Saturated Fatty Acids
 
In saturated fatty acids (SFA), there is only
single carbon-to-carbon bonds, they have a
linear shape
Generally, saturated fatty acids are solid at
room temperature and have high melting
points
 
44
 
Saturated Fatty Acids
 
Increase clotting activity in the bloodstream and
thus develop arterial thickening, which leads to
strokes, heart attack and other forms of damage
Stimulate the production of cholesterol by our
liver
Excessive intake of saturated fats causes an
increase in “bad” cholesterol that impedes blood
flow, and causes more damage to health than
direct consumption of dietary cholesterol
 
45
 
Source: Centre for Health Protection, Department of Health
 
Unsaturated Fatty Acids
 
Fatty acids may also be unsaturated, containing
one or more carbon-to-carbon double bonds
Monounsaturated fatty acids (MUFA) contain
only one double bond, such as oleic acid
Polyunsaturated fatty acids (PUFA) contain two or
more double bonds, such as linoleic and linolenic
acids
Generally, unsaturated fatty acids are liquid at
room temperature and have low melting points
 
46
 
Unsaturated Fatty Acids
 
In polyunsaturated fatty acids, the hydrogen atoms can
be arranged in one of two ways.  One arrangement is
called 
cis
, the other is called 
trans
.
In nature, most unsaturated fatty acids are cis fatty
acids.
Trans fatty acids are produced along with hydrogenated
oil.
Hydrogenation is the process of adding hydrogen to
unsaturated fatty acids to reduce the number of
double bonds.
Small amounts of trans fatty acids occur naturally in
foods like beef, lamb, and dairy products.
 
47
 
Unsaturated Fatty Acids
 
48
 
Cis and trans configuration
The double bonds in fatty acids occur in either cis or the trans
configuration
 
 
 
 
 
 
 
 
The trans double bond has a higher melting point than the cis
configuration
The trans configuration does not significantly change the linear shape of
the molecule (about 42
o
 bend in cis linear hydrocarbon chain)
 
H               H
\          /
C = C
/          \
 
Cis
 - the hydrogen atoms attached to the
carbon atoms of the double bond are
located on the same side of the double
bond
 
Trans
 - the hydrogen atoms are located on
opposite sides of the double bond, across
from one another
 
Sources of Cis Fatty Acids
and Trans Fatty Acids
 
49
 
Monounsaturated Fatty Acids
 
Very beneficial to health
Help to reduce the level of low-density
lipoprotein (also known as “bad” cholesterol)
in the blood stream and prevent blockage of
the arteries
 
50
 
Source: Centre for Health Protection, Department of Health
 
Polyunsaturated Fatty Acids
 
Contain linoleic acid and linolenic acid, both of
which are essential fatty acids that cannot be
produced by our body, and can only be absorbed
through the consumption of food
These kind of fatty acids are very important to
our health
They facilitate blood flow, maintain normal blood
pressure and strengthen the immune system
Moderate amounts of polyunsaturated fats can
reduce levels of total cholesterol (both beneficial
and harmful) in the blood
 
51
 
Source: Centre for Health Protection, Department of Health
 
Cholesterol
 
Sterols
Sterols are round in shape
Cholesterol is the primary animal sterol
Cholesterol is vital to animal cell membrane
structure and functions as a precursor to fat-
soluble vitamins and steroid hormones
 
52
 
Cholesterol
 
A type of lipid of a soft waxy consistency found in
the bloodstream and in the body’s cells
It makes and repairs cell membranes
It produces important hormones (such as sex
hormones), vitamin D and bile acids which help
to digest foods
A large proportion of cholesterol in the human
body is manufactured by the liver, while some is
directly derived from the diet
 
53
 
Source: Centre for Health Protection, Department of Health
 
Cholesterol
 
Being insoluble in water, cholesterol binds to
proteins to become lipoproteins so that it can be
transported in blood
These lipoproteins can broadly be divided into
‘Good’ high-density lipoprotein cholesterol (HDL-C)
‘Bad’ low-density lipoprotein cholesterol (LDL-C)
Different lipoproteins have different effects on
health
In evaluating blood cholesterol level, HDL-C, LDL-
C and triglycerides are usually considered
 
54
 
Source: Centre for Health Protection, Department of Health
 
Cholesterol
 
55
 
Source: Centre for Health Protection, Department of Health
 
Sources of Cholesterol
 
Dietary cholesterol is found in foods of animal
origin such as meat, seafood, egg yolks and
dairy products
Foods of plant origin are cholesterol-free
Too much dietary cholesterol can cause raised
blood cholesterol level, but dietary saturated
fats actually have a 
significant effect in raising
blood cholesterol levels
 
56
 
Source: Centre for Health Protection, Department of Health
 
Sources of Cholesterol
 
57
 
Source: Centre for Health Protection, Department of Health
 
Cholesterol
 
Too much cholesterol in the blood is harmful to health
Excess cholesterol will deposit as plaque on the inner
walls of blood vessels
Over time, this build-up causes hardening, narrowing
or blockage of the vessels that in turn can lead to
coronary heart disease (CHD), stroke and other
vascular diseases
Studies across different populations reveal that those
with higher blood cholesterol levels have more
atherosclerosis (i.e. hardening of arteries) and CHD
than those having lower levels
 
58
 
Source: Centre for Health Protection, Department of Health
 
References
 
Canola Council of Canada
Centre for Health Protection, Department of Health - Diet and
Nutrition. (n.d.).
Centre for Health Protection, Department of Health - Two Plus
Three Every Day.
Centre for Health Protection, Department of Health – Know More
about Fat.
Centre for Health Protection, Department of Health - Non-
Communicable Diseases Watch (Vol. 9).
Insel, P. M., Ross, D., McMahon, K., & Bernstein, M. (2019).
Discovering nutrition.
 Burlington, MA: Jones & Bartlett Learning.
Otten, J. J., Hellwig, J. P., & Meyers, L. D. (2006). 
Dietary reference
intakes: The essential guide to nutrient requirements.
 Washington,
D.C.: National Academies Press.
 
59
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Explore the essential macronutrients including carbohydrates, sugar, proteins, and fats. Learn about their functions, types, food sources, and impact on health. Understand the role of sugar in energy provision and potential health risks. Discover the importance of starch as a common carbohydrate in our diet.

  • Macronutrients
  • Carbohydrates
  • Sugar
  • Proteins
  • Fats
  • Health

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  1. Nutrition and Health Macronutrients

  2. Topics Carbohydrates Sugar Starch Cellulose Proteins Fats and Oils Saturated fatty acids Unsaturated fatty acids Cholesterol 2

  3. CARBOHYDRATES 3

  4. Functions of Carbohydrates Carbohydrate is an energy-giving nutrient It provides energy for: keeping the body warm the body organs to work properly, e.g. breathing, digesting daily activities (e.g. sitting, walking) and other physical activities (e.g. swimming, playing ball games) 4

  5. Types of Carbohydrates There are three types of carbohydrates Sugar Starch Cellulose 5

  6. Sugar What is sugar? Sugar is a quick source of energy It is an empty energy food , because it only provides energy with no other nutrients Sugar on food labels may appear as sucrose, glucose / dextrose, fructose, maltose, lactose, corn syrup, honey, and molasses 6

  7. Sugar Sources of sugar Sugar is present in fruits, vegetables and milk The sugar used everyday is mainly processed from sugar cane or sugar beet 7

  8. Sugar Uses of sugar Sugar is often added to processed foods Hidden sugar is a component of processed food that cannot be seen 8

  9. Sugar Sugar is the main cause of tooth decay Excess sugar will be stored inside body as fat, the result can be overweight 9

  10. Starch What is starch? It consists of a large number of glucose units joined together The most common carbohydrate in the human diet Starch is contained in many staple foods Starchy foods are good sources of energy 10

  11. Starch Sources of starch Starch is stored in many plants Foods that are rich in starch: Food Groups Examples Grains Rice, oats, barley, and wheat - Products that are made from these grains such as noodles, pastas, bread, and crackers Fruits Banana (unripe) Vegetables Potatoes, corn Alternatives Legumes Peas, lentils, kidney beans, red beans, and split peas 11

  12. Starch Dietary requirement For an average adult, starch and sugar should form about 50-60% of the daily energy requirement 12

  13. Dietary Requirement Calorie Percentage 50 - 60 Carbohydrate Protein 10 - 20 Fat < 30 13

  14. Dietary Requirement Protein (1 gram provides 4 kcal) Carbohydrate Fat (1 gram provides 9 kcal) (1 gram provides 3.75 kcal) Energy 14

  15. Dietary Requirement Example: Answer: If carbohydrate forms 55% of daily energy requirement, how much carbohydrate should a person eat in one day? Energy originates from carbohydrate: 1,800 kcal x 55% = 990 kcal (Assume the daily energy requirement for this person is 1,800 kcal.) Amount of carbohydrate to be eaten per day: 990 kcal 3.75 kcal/gram = 264 gram 15

  16. Starch Excess starch will be stored inside body as fat, the result can be overweight 16

  17. Cellulose What is cellulose? Cellulose is found in the wall of plant cells It is the main source of dietary fibre Dietary fibre helps to remove body waste It prevents constipation and other intestinal problems 17

  18. Cellulose Cell wall, contains cellulose, hemicellulose, pectic substances, and lignin Plasma membrane Mitochondria Ribosomes Chloroplast Endoplasmic reticulum Vacuole, holds water and provides crispy texture to vegetables and fruits Nucleus Structure of Vegetables / Fruits 18

  19. Cellulose Sources of cellulose Foods that are rich in cellulose: plant food like whole grain wheat, oat, legumes, cabbage, cauliflower, choy sum, berries, apples, etc. Foods that do not contain cellulose: animal food like pork, beef, fish, etc. 19

  20. Cellulose Dietary requirement Reference value of dietary fibre: not less than 25g per day Department of Health promotes 2 plus 3 a day in order to improve health and reduce risks of chronic diseases Source: Centre for Health Protection, Department of Health 20

  21. Cellulose One serving of fruit is approximately defined as: 2 pieces of small-sized fruits (such as plum, kiwifruit) 1 piece of medium-sized fruit (such as orange, apple) piece of large-sized fruit (such as banana, grapefruit, star fruit) bowl of fruit cuts (such as watermelon, cantaloupe, honeydew melon) bowl of mini-sized fruit (such as grapes, lychees, cherries, strawberries) 1 tablespoon of dried fruits without added sugar or salt (such as raisin, pitted prune) cup of pure fruit juice without added sugar (such as fresh orange juice with pulp) Remark: 1 cup = 240 ml 1 bowl = 250-300 ml Source: Centre for Health Protection, Department of Health 21

  22. Cellulose One serving of vegetables is approximately defined as: 1 bowl of raw leafy vegetables (e.g. lettuce, purple cabbage) bowl of cooked vegetables, sprouts, gourds, beans or mushrooms (e.g. Chinese flowering cabbage, Chinese kale, spinach, white cabbage, bean sprouts, eggplant, carrot, snow pea, Enokitake mushroom) cup of fresh vegetable juice* without added sugar (e.g. fresh tomato juice) Remark: 1 cup = 240 ml 1 bowl = 250-300 ml Source: Centre for Food Safety, Department of Health 22

  23. PROTEINS 23

  24. Functions of Proteins For body growth Repair and replace damaged cells Provide energy 24

  25. What is Protein? Proteins are made up of amino acids The human body needs 20 types of amino acids to build all the proteins needed nine of them are essential amino acids, i.e. cannot be made by the body the rest are non-essential amino acids 25

  26. Types of Protein? There are two types of protein: High biological value (HBV) proteins found in most animal proteins contain a good amount of all the essential amino acids Low biological value (LBV) proteins found in most plant proteins does not supply all the essential amino acids 26

  27. Sources of Proteins High biological value proteins Meat Poultry Fish Milk and dairy products Egg Bean curd Soya bean is the only plant food which provides HBV proteins Low biological value proteins Rice Bread Almonds Mung beans Red beans Cashew Green peas Gluten Dried mushrooms 27

  28. Improving the Protein Quality of a Meal When eating proteins from two different plant sources, the amino acids in one food can supplement the amino acids lacking in the other food In eating a plant protein food with an animal protein food, the biological value of the protein mixture in the meal is also improved 28

  29. Improving the Protein Quality of a Meal Examples of supplementing amino acids with two different foods Cereals Milk Toast Taro Baked beans Chicken wings 29

  30. Proteins Inadequate intake of protein affect growth in children, slow down or even stop growing not common in adults, since most foods contain proteins Excessive intake of protein excessive protein will be turned into energy and stored in our body as fat 30

  31. FATS AND OILS 31

  32. Functions of Fats and Oils Fat stores heat, which can be used as energy when necessary. The layer of fat directly beneath our skin also serves as a kind of insulation, which helps maintain our body temperature. Most fats are found in adipose tissues, which surround and protect our body's internal organs. Fat serves as a medium for transporting and absorbing fat-soluble vitamins such as vitamins A, D, E and K. Fat is an essential ingredient in the production of cholesterol, bile acid, and certain hormones. Fat ensures the proper functioning of our nervous system and our skin. Source: Centre for Health Protection, Department of Health 32

  33. What are Fats and Oils? Fat is a nutrient yielding high amount of energy The amount of energy provided by fat doubles the amount of energy provided by carbohydrates or protein of the same weight People enjoy fats and oils in the diet due to its flavour, mouthfeel, palatability, texture and aroma 33

  34. What are Fats and Oils? Lipids are sometimes used as a synonym for fats Lipids comprise a group of naturally occurring molecules that includes fats, sterols, fat-soluble vitamins, monoglycerides, diglycerides, triglycerides, and phospholipids Two origins: plant and animal Both fats and oils belong to lipids Fat - solid at room temperature Oil - liquid at room temperature They are chemically similar, but differ in physical state 34

  35. Types of Fats and Oils Based on Origin Animal Source Pork fats (bacon, lard) Animal fats (solid at room temp.) Beef/mutton fats (tallow) Poultry fats (chicken fat, duck fat) Dairy fats (butter, ghee) Cod liver oil Marine oils / fish oils (liquid at room temp.) Whale oil Shark liver oil etc. 35

  36. Types of Fats and Oils Based on Origin Cocoa butter Plant Source Fats (solid at room temp.) Coconut oil Palm oil Peanut oil Oils (liquid at room temp.) Sesame oil Sunflower oil Safflower oil Corn oil Cotton seed oil Olive oil 36

  37. Types of Fats and Oils Some fats are visible, some fats are invisible Foods containing visible fats Foods containing invisible fats Cooking oil Butter Margarine Lard Oil floating on soup Salad dressing Potato chips Bakery products Meat sausages Ice-cream 37

  38. Fats and Oils Inadequate intake of fats and oils not common in developed countries can be seen occasionally in developing countries, may hinder absorption of fat soluble vitamins, such as vitamin A, hence causing night blindness Excessive intake of fats and oils excess fat will be stored in our body, and causing overweight and obesity individuals can have higher risk in developing chronic diseases like coronary heart disease, hypercholesterolaemia (high blood cholesterol), etc. 38

  39. Structure and Composition of Fats and Oils Glycerides Glycerides contain a glycerol molecule backbone joined to one or more fatty acid molecules There are monoglycerides, diglycerides, and triglycerides A monoglyceride contains glycerol esterified to one fatty acid molecule Fats and oils are triglycerides, the major constituent of lipids More than 95% of fatty substance in food is triglycerides 39

  40. Structure and Composition of Fats and Oils One fatty acid chain A monoglyceride Glycerol Three fatty acid chains A triglyceride 40

  41. Structure and Composition of Fats and Oils Fatty acids Fatty acids are long hydrocarbon chains with a methyl group (CH3) at one end of the chain and a carboxylic acid group (COOH) at the other Most natural fatty acids contain from 4 to 24 carbon atoms and most contain an even number of carbon atoms in the chain Animal fats typically have 18 carbons in the fatty acid chain These long chains are made of various fatty acids, such as saturated fatty acid, monounsaturated fatty acid and polyunsaturated fatty acid Example of a saturated fatty acid 41

  42. Sources of Fatty Acids Saturated Fatty Acids Monounsaturated Fatty Acids Polyunsaturated Fatty Acids Coconut oil Safflower oil Flaxseed oil Soybean oil Butter Olive oil Palm oil Canola oil Corn oil Sunflower oil Cotton seed oil Lard 42

  43. Sources of Fatty Acids Comparison of composition of dietary fat (Source: Canola Council of Canada) 100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% Saturated Fat Polyunsaturated Fat Alpha Linolenic Monounsaturated Fat 43

  44. Saturated Fatty Acids In saturated fatty acids (SFA), there is only single carbon-to-carbon bonds, they have a linear shape Generally, saturated fatty acids are solid at room temperature and have high melting points 44

  45. Saturated Fatty Acids Increase clotting activity in the bloodstream and thus develop arterial thickening, which leads to strokes, heart attack and other forms of damage Stimulate the production of cholesterol by our liver Excessive intake of saturated fats causes an increase in bad cholesterol that impedes blood flow, and causes more damage to health than direct consumption of dietary cholesterol Source: Centre for Health Protection, Department of Health 45

  46. Unsaturated Fatty Acids Fatty acids may also be unsaturated, containing one or more carbon-to-carbon double bonds Monounsaturated fatty acids (MUFA) contain only one double bond, such as oleic acid Polyunsaturated fatty acids (PUFA) contain two or more double bonds, such as linoleic and linolenic acids Generally, unsaturated fatty acids are liquid at room temperature and have low melting points 46

  47. Unsaturated Fatty Acids In polyunsaturated fatty acids, the hydrogen atoms can be arranged in one of two ways. One arrangement is called cis, the other is called trans. In nature, most unsaturated fatty acids are cis fatty acids. Trans fatty acids are produced along with hydrogenated oil. Hydrogenation is the process of adding hydrogen to unsaturated fatty acids to reduce the number of double bonds. Small amounts of trans fatty acids occur naturally in foods like beef, lamb, and dairy products. 47

  48. Unsaturated Fatty Acids Cis and trans configuration The double bonds in fatty acids occur in either cis or the trans configuration H H \ / C = C / \ H H \ / C = C / \ H H Trans - the hydrogen atoms are located on opposite sides of the double bond, across from one another Cis - the hydrogen atoms attached to the carbon atoms of the double bond are located on the same side of the double bond The trans double bond has a higher melting point than the cis configuration The trans configuration does not significantly change the linear shape of the molecule (about 42o bend in cis linear hydrocarbon chain) 48

  49. Sources of Cis Fatty Acids and Trans Fatty Acids Cis Fatty Acids Trans Fatty Acids Flaxseed oil Margarine Soybean oil Shortening Crisps and snacks Corn oil Packaged desserts, cakes, and pastries Cotton seed oil 49

  50. Monounsaturated Fatty Acids Very beneficial to health Help to reduce the level of low-density lipoprotein (also known as bad cholesterol) in the blood stream and prevent blockage of the arteries Source: Centre for Health Protection, Department of Health 50

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