High Volume Fly Ash Concrete in Civil Engineering

 
CIVIL ENGINEERING
MATERIALS LAB
III SEMESTER
3CE4-24
 
 
 
PROPERTIES 
OF
HIGH 
VOLUME
FLY 
ASH
 
CONCRETE
 
1
 
OVERVIEW
 
INTRODUCTION
PROPERTIES 
OF 
FRESH 
HVFA
 
CONCRETE
PROPERTIES 
OF 
HARDENED 
HVFA
 
CONCRETE
CONCLUSION
 
2
 
INTRODUCTION
 
Fly 
ash 
concrete 
is an eco-friendly construction material
in which fly ash 
replaces 
a 
part 
of 
Portland
 
cement.
 
Bu
t
 
IS:45
6
 
 
2
0
0
0
 
and
 
A
CI:318
 
allows
 
r
eplaceme
nt
 
o
f
OPC
 
by
 
Fly ash up to 35%
 
only
 
as
 
binding
 
material.
 
H
i
g
h
 
v
o
l
u
m
e
 
fly
 
ash
 
con
c
r
et
e
 
is
 
a
 
c
onc
r
et
e
 
whe
r
e
a
 
replacement
 
of
  
about 
35% 
or
 
more
 
of
 
cement is
made with the usage 
of 
fly
 
ash.
 
3
 
WHAT 
IS 
FLY
 
ASH?
 
Fly ash is a finely divided 
byproduct resulting 
from
 
the
 
combustion 
of 
coal in power
 
plants.
 
It contains 
large 
amounts 
of 
silica, alumina and 
small
amount 
of 
unburned carbon, 
which
 
pollutes
environment.
 
It is 
grey 
in 
colour 
and alkaline in
 
nature.
The 
particle 
size 
ranges 
between 
1-100
 
microns.
The specific gravity 
of 
FA 
lies between 1.9 and
 
2.8
(generally 3.15 for
 
Cement)
 
4
 
The 
surface area is typically 
300–500 m
2
/kg,
 
although
 
some FA can have a 
surface 
area as high as 
700
m
2
/kg ( around 330 
m
2
/kg 
for Cement
 
)
 
The 
mass per unit volume 
including 
air between
particles ( density ) can vary from 540 to 860
 
kg/m3.
 
5
 
Classification 
of 
Fly
 
Ash
 
Two 
classes 
of 
fly ash 
are 
defined by 
ASTM
 
C618:
Class 
F fly
 
ash
Class 
C fly
 
ash
This 
classification is based on the chemical
composition 
of 
FA 
i.e. the 
sum 
of 
silica, alumina and
iron 
oxide 
percentages 
in the 
FA, 
being
 
:
minimum 
of 
70% 
for a 
Class
 
F
minimum 
50% 
for a Class
 
C
 
6
undefined
 
7
 
SOURCE:
www.caer.uky.edu/kyasheducation/flyash.sht
ml
 
SOURCE:
 
www.gradjevinarstvo.rs
 
ISSUES WITH
 
OPC
 
Conventional 
Portland 
Cement is the 
most
 
consumed
commodity in the 
world 
after
 
water.
It 
is also the 
most 
energy 
intensive
 
material
Cement 
production 
leads 
to 
high 
carbon-dioxide
 
emission.
CO
2 
is 
the 
primary 
green 
house 
gas that causes global
 
warming
manufacturing 
of 
cement accounts for 6 to 7% 
of 
the 
CO
2 
that
humans
 
produce.
It is 
produced 
by 
calcination 
of 
limestone and burning 
of
 
fossil
fuels
 
8
 
WHY 
TO 
USE 
FLY
 
ASH?
 
being 
a pozzolanic, it 
can 
actually 
replace 
a 
part 
of
Portland
 
cement
results 
in 
more 
durable
 
concrete
high ultimate
 
strength
improves
 workability
improves 
cost economy 
of
 
concrete
reduction 
in 
heat 
of
 
hydration
decreases 
density 
of
 
concrete
more 
environment 
friendly
 
concrete.
 
9
 
EFFECT OF 
HIGH 
VOLUME
 
OF 
FLY 
ASH
ON 
PROPERTIES 
OF
 
FRESH
 
CONCRETE
 
1.
 
WORKABILITY
2. 
SETTING 
TIME, 
BLEEDING AND
 
SEGREGATION
3. 
HEAT 
OF
 
HYDRATION
4.
 
DENSITY
 
10
 
WORKABILITY
 
The 
inclusion 
of 
high 
volume of fly ash 
increases the
workability 
as the content of FA is
 
increased.
 
The 
increment 
in 
the 
slump 
height 
is about 40%
and 54% with the 
inclusion 
of 
45% and 50% 
FA,
respectively.
generally 
higher 
substitution 
of Portland cement by
fly ash 
reduces 
the water 
requirement 
for
obtaining a given
 
workability
 
11
undefined
 
. Effect 
of 
fly ash 
fineness & %
 
on
water demand 
of
 
concrete
 
12
 
WORKABILITY
 
reduction 
in water 
requirement 
is 
mainly 
due to 
three
 
mechanisms:
 
 
Fly ash gets 
absorbed 
on the 
surface 
of 
oppositely 
charged
cement 
particles 
and 
prevent 
them 
from 
flocculation, 
releasing
large 
amounts 
of 
water, 
thereby reducing 
the water-demand for a
given
 workability.
 
The 
spherical 
shape 
and the 
smooth 
surface 
of 
fly 
ash
 
particles
help to 
reduce 
the 
interparticle 
friction and thus 
facilitate
 
mobility
 
 
Due to 
its 
lower 
density 
and 
higher volume per 
unit 
mass, 
fly 
ash 
is a
more 
efficient void-filler 
than 
Portland
 
cement.
 
13
 
Contributions of enhanced
 
workability:
 
Light 
weight concrete is easier to pump as pumping
requires 
less
 
energy.
Improved
 
finishing
Reduced 
segregation 
and bug
 
holes
Reduced
 
Bleeding
Less 
sand 
is 
needed in the 
mix 
to produce required
workability.
 
14
 
 
Back…
 
SETTING
 
TIME
 
High 
volume 
of 
fly ash 
extends both the 
initial 
and
final setting 
time 
of
 
concrete
The 
impact 
of 
fly ash on the setting 
behavior 
of
concrete 
is dependent
 
on:
composition 
and quantity 
of 
fly ash
 
used
amount 
of
 cement
water - to – 
cementitious material
 
ratio
concrete
 temperature
 
15
undefined
 
Effect of FA content on penetration resistance of
setting 
concrete
 
mixture
 
16
 
Bleeding and
 
Segregation
 
The 
inclusion 
of 
high 
volume 
of 
fly ash in the
mixture 
reduces 
the 
bleeding and
 
segregation.
Reason:
the 
rate 
and 
amount 
of 
bleeding 
decreases 
due 
to
the 
reduced 
water
 
demand.
The 
reduction 
of 
bleeding 
and 
segregation 
may be
related 
to the 
lubricating 
effect 
of 
the 
glassy spherical
FA
 
particles.
 
17
 
 
Back…
 
HEAT 
OF
 
HYDRATION
 
Both 
the 
maximum rate 
of 
heat evolution 
and the
cumulative heat evolution 
decrease with the
inclusion 
of 
45% 
FA 
during the 
first 
72
 
hours.
The 
inclusion 
of 
45% 
FA 
results 
in 36% 
reduction 
in
the cumulative 
heat
 
evolution.
In 
addition, the time 
of 
reaching 
the maximum 
rate
of 
heat 
evolution
 
delays.
 
18
 
Effect of fly ash 
on 
heat of
 
hydration
 
19
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by
Michael 
Thomas
 
(www.cement.org)
 
Effect of fly 
ash 
on temperature
 
rise
 
20
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by
 
Michael
 
Thomas
 
(www.cement.org)
 
 
Back…
 
D
E
N
S
I
T
Y
 
Inclusion 
of 
high 
volume 
of 
fly ash in 
the 
mixture
decreases 
its 
density 
which leads to a 
reduction 
in
the dead weight 
of 
the constructed
 
element.
Reason:
This 
reduction 
in the density 
could 
be 
attributed 
to the
lower specific gravity 
of 
FA 
(1.9 to 
2.8) 
as 
compared 
to
cement
 
(3.15)
 
21
 
 
Back…
 
EFFECT 
OF 
HIGH 
VOLUME
 
OF 
FLY 
ASH 
ON
PROPERTIES 
OF 
HARDENED
 
CONCRETE
 
1. 
COMPRESSIVE
 
STRENGH
 
2.
 DURABILITY
 
22
 
COMPRESSIVE
 
STRENGH
 
TEST
5 
mixtures 
were 
considered 
, 3 
of 
them with OPC
and 
varying 
FA 
content, and 2 
control 
pastes using
100% 
OPC or 100% 
BC.
conducted 
using 40%, 
60% 
and 80% 
FA
replacement 
by 
volume 
of
 
cement
 
maintaining the w/b by mass 
constant 
at
 
0.42
 
23
 
MIXTURE 
PROPORTIONS 
OF THE
 
PASTES
 
24
 
SOURCE: 
Felipe 
Rivera, 
Patricia 
Martínez, 
Javier Castro, 
Mauricio López “Massive 
volume 
fly ash
concrete”, 
Cement and 
Concrete 
Composites, 
Volume 
63, 
October
 
2015
 
The 
cement pastes were prepared in a mechanical 
mixer
 
50-mm 
cube 
specimens 
were cast 
(3 specimens 
per
 
age)
At 
the age of 24 h, the specimens 
were 
demolded and
placed in vacuum 
sealed 
plastic bags in a moist room,
(95 ± 3)% 
RH 
and (23 ± 2)˚C, until the age 
of
 
testing.
 
25
 
26
 
SOURCE
: 
Felipe Rivera, Patricia Martínez, Javier Castro, Mauricio 
López 
“Massive 
volume fly ash
concrete”, Cement 
and 
Concrete Composites, Volume 63, October
 
2015
 
The 
compressive strength gain after 
3 
d, 
7 
d, 28 
d 
and 90 
d 
for each
 
mixture
 
The 
compressive 
strength 
of 
the 
40-F 
paste is
 
similar
 
to that 
of 
the OPC paste 
at 
any
 
age
while 
that 
of 
the 60-F 
paste 
is 
very 
similar 
to the BC
paste at early ages (3 d and 7 
d) 
and 
higher at 28 d
and 
90
 
d.
The 
compressive 
strength 
of the 
80-F 
paste 
is 
lower
than that of the BC paste at any age; its 
strength 
can
reach up to 22 MPa at 28 d and 35 MPa at 90
 
d.
 
27
undefined
 
28
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by 
Michael
 
Thomas
(www.cement.org)
 
Rate 
of 
strength
 
gain
 
The 
rate 
of 
strength 
gain in the 
FA-F 
pastes
increases 
with the 
replacement
 
level.
Between 
28 d and 90 d, the 
strength 
gain 
of 
OPC
paste is similar to that 
of 
the BC paste but 
lower
than that 
of 
the 80-F paste (≈0.21
 
MPa/d).
For 
the 40-F and 60-F pastes, the 
strength 
gains 
are
the 
lowest 
(≈0.07 
MPa/d 
and 0.08 
MPa/d,
respectively), 
between 28 d and 90
 
d.
 
29
 
 
Back…
 
DURABILITY
 
Abrasion
 
Resistance
The 
mix 
containing 
70% 
FA 
exhibits 
a 
slightly 
lower 
abrasion
value than 
the 
concrete 
containing 
50% 
FA 
and OPC
concrete
although 
70% 
FA 
exhibits 
a 
higher 
abrasion 
value below 
a
certain 
compressive
 
strength.
The 
abrasion 
resistance 
is mainly 
dependent 
on the
compressive strength 
of
 
concrete.
It 
is assumed that C-S-H 
of 
50% 
FA 
or 
OPC 
provide 
better
cohesion 
to 
the 
aggregate-sand-paste 
and 
therefore 
better
resist 
the action 
of 
surface 
shear
 
forces.
 
30
 
Permeability 
and Resistance to 
Penetration 
of
 
Chlorides
Fly 
ash 
reduces 
permeability 
of 
concrete to water and
gas 
provided 
the 
concrete 
is adequately 
cured, 
due to
 
a
 
refinement 
in the 
pore
 
structure.
Through 
pozzolanic 
activity, 
fly ash chemically combines
with water and CaOH
2 
– forming additional cementitious
compounds, 
therefore
 
:
it 
is 
not subject 
to
 
leaching
it decreases 
bleed channels, 
capillary 
channels 
and 
void
spaces and 
thereby 
reduces
 
permeability.
 
31
 
With 
the 
use 
of fly ash, 
concrete 
becomes nearly 
impermeable to
c
si
h
g
l
n
o
i
r
fi
i
c
d
a
e
n
s
tl
a
y
n
. 
d the 
rate 
of 
chloride penetration
 
decreases
 
32
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by 
Michael 
Thomas
 
(www.cement.org)
 
Alkali- Silica
 
Reaction
 
Class 
F fly ash is 
capable 
of 
controlling 
alkali – 
silica 
reaction
in 
concrete 
even 
at moderate 
levels 
of 
replacement 
(20%
 
to
 
30%)
Reason : 
concentration 
of 
alkali 
hydroxides 
is 
reduced 
in
 
the
pore 
solution 
when fly ash is
 
present
The 
level 
of 
fly ash 
required 
to 
suppress 
expansion 
of
concrete 
increases
 
with:
Increased 
calcium and 
alkali 
content 
of 
fly
 
ash;
Decreased 
silica content 
of 
fly
 ash;
Increased 
aggregate reactivity;
Increased 
alkali 
availability 
from 
Portland cement
 
and
environment
 
33
 
 
There 
is 
low 
risk of 
concrete expansion occurring in 
the
 
field
 
when very 
high volume 
fly ash 
concrete 
with 
50% 
or 
more
 
fly
 
ash 
is
 
used.
 
34
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by 
Michael 
Thomas
(www.cement.org)
 
Sulfate
 
Resistance
HVFA 
concrete 
specimens exhibit 
higher
 
sulfate
 
resistance. The specimens containing 
60% 
FA
 
as
 
cement 
replacement 
exhibited 
better 
performance
in lactic/acetic and sulfuric
 
acid
 
FA 
induces 
three 
phenomena 
which 
improves
sulfate
 
resistance:
 
consumes 
the 
free 
lime 
resulting 
it 
unavailable to
 
react
 
with
 
sulfate,
 
reduces 
permeability which 
prevents 
sulfate penetration,
 
and
by 
replacing 
cement, 
the 
reactive 
aluminates 
are 
reduced.
reduced.
 
35
 
Carbonation 
and 
Corrosion
 
Resistance
 
When 
concrete 
specimens 
are 
exposed 
to 
different
methods 
of 
carbonation, 
the 
results 
show 
a 
reduction
 
in
 
the 
carbonation resistance 
of 
concrete specimens
 
with
 
the 
inclusion 
of 
50% 
FA 
as 
cement
 
replacement.
Therefore 
there 
is 
increase 
in the 
carbonation 
depth 
of
concrete
 
specimens
in 
areas 
prone 
to 
carbonation, 
particular 
attention must
be paid to 
ensure
 
suitable:
concrete mix
 
proportions,
period 
of 
moist 
curing,
 
and
depth 
of
 
cover
 
36
undefined
 
37
 
Source
: 
optimizing-the-use-of-fly-ash-in-concrete 
– by 
Michael 
Thomas
(www.cement.org)
 
Resistance to Cyclic 
Freezing 
and 
Thawing, 
and Deicer 
Salt
 
Scaling
Concrete 
can be 
resistant 
to cyclic 
freezing 
and thawing
 
provided:
 
38
 
it 
has 
sufficient
 
strength
an adequate air 
void
 
system
the 
aggregates 
are 
frost
 
resistant.
This holds 
true for fly ash
 
concrete
concrete 
containing 
fly 
ash 
is less 
resistant to scaling when
subjected to 
freezing 
and thawing 
in 
presence 
of 
deicer
 
salts.
For 
fly 
ash 
concrete 
structures 
exposed to 
de-icing 
salts the
following 
observations 
have been
 
made:
scaling increases 
as the w/cm
 
increases
scaling 
mass loss 
increases 
with fly ash
 
content
the 
use 
of 
curing 
compounds 
reduces
 
scaling
 
 
Back…
 
C
ON
C
L
USI
O
N
 
Use 
of 
high 
volume 
fly ash 
concrete 
in construction 
is one big 
step
in natural 
resource 
conservation 
and it 
needs 
to be 
promoted 
all
over 
the
 
world.
In fact, 
we 
can call high volume 
fly ash 
concrete 
as a 
green
concrete, since 
it 
can 
protect 
the 
environment 
from 
global warming
and at the 
same time 
from 
pollution.
There 
may be 
some negativity 
attached to it like 
slower
construction rates 
as it 
gains 
strength 
slowly and gives lower 
early
strengths.
But, 
the 
same can 
be 
ignored 
as the 
later 
strengths 
(90 days or
more) 
and durability 
of 
high 
volume 
fly ash 
concrete 
is 
much better
than plain
 
concrete.
 
39
 
Clearly 
there is no one replacement level best suited
 
for
 
all applications.
The 
inclusion 
of high volume fly ash in the 
mixture
causes
 
:
Reduced 
the 
heat 
of hydration, bleeding, 
segregation,
density, but increased workability and setting
 
time.
Decreased 
the mechanical 
strength 
especially at 
early
ages with increasing FA
 
content.
Increased 
durability of
 
concrete
reduced 
resistance against Deicer Salt
 
Scaling.
 
40
undefined
 
Product
 
Comparisons
 
High 
Volume 
Fly
 
Ash
Concrete
Less 
energy
 
intensive
manufacture
Higher 
ultimate
 
strength
More
 
durable
Uses a waste
 
by-product
Less global 
warming
 
gases
created
 
Conventional
 
Concrete
Energy 
intensive
manufacturing
Weaker 
ultimate
 
strength
Less
 
durable
Uses 
virgin 
material
More 
global
 
warming
gases
 
created
undefined
 
43
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High Volume Fly Ash Concrete is an eco-friendly alternative in construction, where fly ash partially replaces Portland cement. This material offers several benefits but is limited to specific replacement percentages. Understanding the properties, compositions, and benefits of using fly ash concrete can lead to more sustainable construction practices.

  • Fly Ash Concrete
  • Civil Engineering
  • Sustainable Construction
  • Eco-friendly Material
  • High Volume Concrete

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  1. CIVIL ENGINEERING MATERIALS LAB III SEMESTER 3CE4-24

  2. PROPERTIES OF HIGH VOLUME FLY ASH CONCRETE 1

  3. OVERVIEW 2 INTRODUCTION PROPERTIES OF FRESH HVFA CONCRETE PROPERTIES OF HARDENED HVFA CONCRETE CONCLUSION

  4. INTRODUCTION 3 Fly ash concrete is an eco-friendly construction material in which fly ash replaces a part of Portland cement. But IS:456 2000 and ACI:318 allows replacement of OPCby Fly ash up to 35% only as binding material. High volume fly ash concrete is a concrete where a replacement of about 35% or more of cement is made with the usage of fly ash.

  5. WHAT IS FLY ASH? Fly ash is a finely divided byproduct resulting from the combustion of coal in power plants. It contains large amounts of silica, alumina and small amount of unburned carbon, which pollutes environment. It is grey in colour and alkaline in nature. The particle size ranges between 1-100 microns. The specific gravity of FA lies between 1.9 and 2.8 (generally 3.15 for Cement) 4

  6. 5 The surface area is typically 300 500 m2/kg, although some FA can have a surface area as high as 700 m2/kg ( around 330 m2/kg for Cement ) The mass per unit volume including air between particles ( density ) can vary from 540 to 860 kg/m3.

  7. Classification of Fly Ash 6 Two classes of fly ash are defined by ASTM C618: Class F fly ash Class C fly ash This classification is based on the chemical composition of FA i.e. the sum of silica, alumina and iron oxide percentages in the FA, being : minimum of 70% for a Class F minimum 50% for a Class C

  8. 7 SOURCE: www.caer.uky.edu/kyasheducation/flyash.sht ml SOURCE: www.gradjevinarstvo.rs

  9. ISSUES WITH OPC 8 Conventional Portland Cement is the most consumed commodity in the world after water. It is also the most energy intensive material Cement production leads to high carbon-dioxide emission. CO2 is the primary green house gas that causes global warming manufacturing of cement accounts for 6 to 7% of the CO2 that humans produce. It is produced by calcination of limestone and burning of fossil fuels

  10. WHY TO USE FLY ASH? 9 being a pozzolanic, it can actually replace a part of Portland cement results in more durable concrete high ultimate strength improves workability improves cost economy of concrete reduction in heat of hydration decreases density of concrete more environment friendly concrete.

  11. EFFECT OF HIGH VOLUME OF FLY ASH ON PROPERTIES OF FRESH CONCRETE 10 1. WORKABILITY 2. SETTING TIME, BLEEDING AND SEGREGATION 3. HEAT OF HYDRATION 4. DENSITY

  12. WORKABILITY 11 The inclusion of high volume of fly ash increases the workability as the content of FA is increased. The increment in the slump height is about 40% and 54% with the inclusion of 45% and 50% FA, respectively. generally higher substitution of Portland cement by fly ash reduces the water requirement for obtaining a given workability

  13. 12 . Effect of fly ash fineness & % on water demand of concrete

  14. WORKABILITY 13 reduction in water requirement is mainly due to three mechanisms: Fly ash gets absorbed on the surface of oppositely charged cement particles and prevent them from flocculation, releasing large amounts of water, thereby reducing the water-demand for a given workability. The spherical shape and the smooth surface of fly ash particles help to reduce the interparticle friction and thus facilitate mobility Due to its lower density and higher volume per unit mass, fly ash is a more efficient void-filler than Portland cement.

  15. Contributions of enhanced workability: 14 Light weight concrete is easier to pump as pumping requires less energy. Improved finishing Reduced segregation and bug holes Reduced Bleeding Less sand is needed in the mix to produce required workability. Back

  16. SETTING TIME 15 High volume of fly ash extends both the initial and final setting time of concrete The impact of fly ash on the setting behavior of concrete is dependent on: composition and quantity of fly ash used amount of cement water - to cementitious material ratio concrete temperature

  17. 16 Effect of FA content on penetration resistance of setting concrete mixture

  18. Bleeding and Segregation 17 The inclusion of high volume of fly ash in the mixture reduces the bleeding and segregation. Reason: the rate and amount of bleeding decreases due to the reduced water demand. The reduction of bleeding and segregation may be related to the lubricating effect of the glassy spherical FA particles. Back

  19. HEAT OF HYDRATION 18 Both the maximum rate of heat evolution and the cumulative heat evolution decrease with the inclusion of 45% FA during the first 72 hours. The inclusion of 45% FA results in 36% reduction in the cumulative heat evolution. In addition, the time of reaching the maximum rate of heat evolution delays.

  20. Effect of fly ash on heat of hydration 19 Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org)

  21. Effect of fly ash on temperature rise 20 Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org) Back

  22. DENSITY 21 Inclusion of high volume of fly ash in the mixture decreases its density which leads to a reduction in the dead weight of the constructed element. Reason: This reduction in the density could be attributed to the lower specific gravity of FA (1.9 to 2.8) as compared to cement (3.15) Back

  23. EFFECT OF HIGH VOLUME OF FLY ASH ON PROPERTIES OF HARDENED CONCRETE 22 1. COMPRESSIVE STRENGH 2. DURABILITY

  24. COMPRESSIVE STRENGH 23 TEST 5 mixtures were considered , 3 of them with OPC and varying FA content, and 2 control pastes using 100% OPC or 100% BC. conducted using 40%, 60% and 80% FA replacement by volume of cement maintaining the w/b by mass constant at 0.42

  25. MIXTURE PROPORTIONS OF THE PASTES 24 Cement Fly ash Fly ash Water Mixture ID (kg/m3) (%) (kg/m3) (kg/m3) 1359.7 0 0.0 571.1 OPC 1307.5 0 0.0 549.1 BC 864.4 40 434.5 545.5 40-F 594.0 60 671.7 531.6 60-F 306.4 80 924.0 516.7 80-F SOURCE: Felipe Rivera, Patricia Mart nez, Javier Castro, Mauricio L pez Massive volume fly ash concrete , Cement and Concrete Composites, Volume 63, October 2015

  26. The cement pastes were prepared in a mechanical mixer 25 50-mm cube specimens were cast (3 specimens per age) At the age of 24 h, the specimens were demolded and placed in vacuum sealed plastic bags in a moist room, (95 3)% RH and (23 2) C, until the age of testing.

  27. The compressive strength gain after 3 d, 7 d, 28 d and 90 d for each mixture 26 SOURCE: Felipe Rivera, Patricia Mart nez, Javier Castro, Mauricio L pez Massive volume fly ash concrete , Cement and Concrete Composites, Volume 63, October 2015

  28. 27 The compressive strength of the 40-F paste is similar to that of the OPC paste at any age while that of the 60-F paste is very similar to the BC paste at early ages (3 d and 7 d) and higher at 28 d and 90 d. The compressive strength of the 80-F paste is lower than that of the BC paste at any age; its strength can reach up to 22 MPa at 28 d and 35 MPa at 90 d.

  29. 28 Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org)

  30. Rate of strength gain 29 The rate of strength gain in the FA-F pastes increases with the replacement level. Between 28 d and 90 d, the strength gain of OPC paste is similar to that of the BC paste but lower than that of the 80-F paste ( 0.21 MPa/d). For the 40-F and 60-F pastes, the strength gains are the lowest ( 0.07 MPa/d and 0.08 MPa/d, respectively), between 28 d and 90 d. Back

  31. DURABILITY 30 Abrasion Resistance The mix containing 70% FA exhibits a slightly lower abrasion value than the concrete containing 50% FA and OPC concrete although 70% FA exhibits a higher abrasion value below a certain compressive strength. The abrasion resistance is mainly dependent on the compressive strength of concrete. It is assumed that C-S-H of 50% FA or OPC provide better cohesion to the aggregate-sand-paste and therefore better resist the action of surface shear forces.

  32. 31 Permeability and Resistance to Penetration of Chlorides Fly ash reduces permeability of concrete to water and gas provided the concrete is adequately cured, due to a refinement in the pore structure. Through pozzolanic activity, fly ash chemically combines with water and CaOH2 forming additional cementitious compounds, therefore : it is not subject to leaching it decreases bleed channels, capillary channels and void spaces and thereby reduces permeability.

  33. 32 With the use of fly ash, concrete becomes nearly impermeable to cs ihglnoirf iicdaenst layn. d the rate of chloride penetration decreases Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org)

  34. Alkali- Silica Reaction Class F fly ash is capable of controlling alkali silica reaction in concrete even at moderate levels of replacement (20% to 30%) Reason : concentration of alkali hydroxides is reduced in the pore solution when fly ash is present The level of fly ash required to suppress expansion of concrete increases with: Increased calcium and alkali content of fly ash; Decreased silica content of fly ash; Increased aggregate reactivity; Increased alkali availability from Portland cement and environment 33

  35. There is low risk of concrete expansion occurring in the field when very high volume fly ash concrete with 50% or more fly ash is used. 34 Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org)

  36. Sulfate Resistance HVFA concrete specimens exhibit higher sulfate resistance. The specimens containing 60% FA as 35 cement replacement exhibited better performance in lactic/acetic and sulfuric acid FA induces three phenomena which improves sulfate resistance: consumes the free lime resulting it unavailable to react with sulfate, reduces permeability which prevents sulfate penetration, and by replacing cement, the reactive aluminates are reduced. reduced.

  37. Carbonation and Corrosion Resistance When concrete specimens are exposed to different methods of carbonation, the results show a reduction in the carbonation resistance of concrete specimens with the inclusion of 50% FA as cement replacement. Therefore there is increase in the carbonation depth of concrete specimens in areas prone to carbonation, particular attention must be paid to ensure suitable: concrete mix proportions, period of moist curing, and depth of cover 36

  38. 37 Source: optimizing-the-use-of-fly-ash-in-concrete by Michael Thomas (www.cement.org)

  39. Resistance to Cyclic Freezing and Thawing, and Deicer Salt Scaling Concrete can be resistant to cyclic freezing and thawing provided: 38 it has sufficient strength an adequate air void system the aggregates are frost resistant. This holds true for fly ash concrete concrete containing fly ash is less resistant to scaling when subjected to freezing and thawing in presence of deicer salts. For fly ash concrete structures exposed to de-icing salts the following observations have been made: scaling increases as the w/cm increases scaling mass loss increases with fly ash content the use of curing compounds reduces scaling Back

  40. CONCLUSION Use of high volume fly ash concrete in construction is one big step in natural resource conservation and it needs to be promoted all over the world. In fact, we can call high volume fly ash concrete as a green concrete, since it can protect the environment from global warming and at the same time from pollution. There may be some negativity attached to it like slower construction rates as it gains strength slowly and gives lower early strengths. But, the same can be ignored as the later strengths (90 days or more) and durability of high volume fly ash concrete is much better than plain concrete. 39

  41. Clearly there is no one replacement level best suited for all applications. The inclusion of high volume fly ash in the mixture causes : Reduced the heat of hydration, bleeding, segregation, density, but increased workability and setting time. Decreased the mechanical strength especially at early ages with increasing FA content. Increased durability of concrete reduced resistance against Deicer Salt Scaling. 40

  42. Product Comparisons Conventional Concrete Energy intensive manufacturing Weaker ultimate strength Less durable Uses virgin material More global warming gases created High Volume Fly Ash Concrete Less energy intensive manufacture Higher ultimate strength More durable Uses a waste by-product Less global warming gases created

  43. 43

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