Challenges and Opportunities in Addressing High-GWP HFCs in Mobile Air Conditioning: Insights from UNEP Workshop

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Session 3: Challenges and opportunities in addressing
high-GWP HFCs in mobile air-conditioning 
Overview
Pega Hrnjak
pega@illinois.edu
Co-Director ACRC,
Will Stoecker Res. Professor,
University of Illinois, Urbana-Champaign, USA
President, CTS
Creative Thermal Solutions
 UNEP Workshop on hydrofluorocarbon management:
technical issues, Bangkok, 20 - 21 April 2015
Unique sector – uniquely addressed
Only one refrigerant - R134a
Industry strongly prefers that status to hold
The only already regulated – EU MAC Directive
Significant experience accumulated
Situation
Real pressure for GWP reduction in Europe, mostly
on European OEMs (and transferred to suppliers)
US and Asian manufacturers address the issues at
European market knowing that development in
Europe will spill over to other regions
One thing is definitive:
MAC is applications where high-GWP HFC (R134a) used is
demonstrated to be replaceable with several options
The question what is 
the best option 
still remains 
R1234yf current replacement refrigerant
Historically
Competition between CO
2
 and R134a (with
indirect system considered) ended in selection of
R1234yf in 2008
Some refrigerant manufacturers felt excluded and
presented competitive approaches which ended
being mixtures (R445A as an example)
After Daimler’s report of 
R1234yf flammability
issues work on its reduction was strengthened to
the extent that CO
2
 as refrigerant was again
strongly supported by some OEMs
What happened during CO
2
 vs. R134a era
Earlier R134a systems may not have been
optimized for efficiency
Excellent and motivated engineers realized
systems with once disregarded refrigerant (CO
2
) to
perform equally or better than R134a
That competition pushed proponents of R134a to
improve system efficiency by adopting almost
everything developed for CO
2
In several steps over ten years we have seen:
Technology improvements in 10 years as a
consequence of refrigerant competition
 
25
o
C
35
o
C
35
o
C
25
o
C
Improvement of efficiency for each
system over 10 years at any condition is
greater than the difference in system
efficiency at any given time.
>>
(900 rpm)
(2000 rpm)
1.
Internal HX 
(result: IHX in R134a MAC systems)
2.
Evaporator and the control
        
(result: microchannel evaporators for R134a).
3.
CO
2
 comp efficiency is high.
4.
Work recovery devices: expanders/ejectors
           (result: first R134a ejector systems in Prius)
Some realized improvements :
Feb 22, 2006
DENSO Develops Unique Double-pipe Internal Heat Exchanger for Front
Car Air Conditioning Systems: New pipe increases cooling performance
by up to 12 percent
 May 20, 2009 KARIYA, Japan ― DENSO Corp. said this week it has developed the
world’s first passenger vehicle air conditioning system that uses
 
ejector technology
. The
ejector, which is a small refrigerant injector, contributes to an overall reduction in power
consumption.
 
The system will be installed on the new Prius, introduced by Toyota this
month
.
(result: R134a Cp w/o suction valve)
Consequently
All improvements made for R134a initiated by CO
2
were lately applied to R1234yf
Additional competition or demands may push new
frontiers
New high glide options are potentially more cost
effective but require further modification of the
cycle and HXs to overcome challenging drop-in
replacement
Current R134a replacement may
not be the winner yet
R134a is already in phase out process with R1234yf
Maybe more costly CO
2
 performs in a/c mode
better at lower temperatures and in more compact
systems
R1234yf easier at higher ambient temperatures
In the case of strengthening the importance of
electric vehicles
, CO
2
 gains the ground because no
refrigerant comes close
R445A also better than R1234yf in heat pumping
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The UNEP workshop in Bangkok discussed technical issues related to high-GWP HFC management in mobile air conditioning. Experts highlighted the pressure for GWP reduction in Europe, the historical competition between CO2 and R134a, and advancements in technology over the past decade in refrigerant systems. The industry's preference for the status quo with R134a and the search for the best replacement option, such as R1234yf, were key points of discussion.

  • High-GWP
  • HFCs
  • Mobile Air Conditioning
  • UNEP Workshop
  • Refrigerant Systems

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  1. UNEP Workshop on hydrofluorocarbon management: technical issues, Bangkok, 20 - 21 April 2015 Session 3: Challenges and opportunities in addressing high-GWP HFCs in mobile air-conditioning Overview Pega Hrnjak pega@illinois.edu Co-Director ACRC, Will Stoecker Res. Professor, University of Illinois, Urbana-Champaign, USA President, CTS Creative Thermal Solutions

  2. Pega Hrnjak 2/8 Unique sector uniquely addressed Only one refrigerant - R134a Industry strongly prefers that status to hold The only already regulated EU MAC Directive Significant experience accumulated

  3. Pega Hrnjak 3/8 Situation Real pressure for GWP reduction in Europe, mostly on European OEMs (and transferred to suppliers) US and Asian manufacturers address the issues at European market knowing that development in Europe will spill over to other regions One thing is definitive: MAC is applications where high-GWP HFC (R134a) used is demonstrated to be replaceable with several options The question what is the best option still remains R1234yf current replacement refrigerant

  4. Pega Hrnjak 4/8 Historically Competition between CO2 and R134a (with indirect system considered) ended in selection of R1234yf in 2008 Some refrigerant manufacturers felt excluded and presented competitive approaches which ended being mixtures (R445A as an example) After Daimler s report of R1234yf flammability issues work on its reduction was strengthened to the extent that CO2 as refrigerant was again strongly supported by some OEMs

  5. Pega Hrnjak 5/8 What happened during CO2 vs. R134a era Earlier R134a systems may not have been optimized for efficiency Excellent and motivated engineers realized systems with once disregarded refrigerant (CO2) to perform equally or better than R134a That competition pushed proponents of R134a to improve system efficiency by adopting almost everything developed for CO2 In several steps over ten years we have seen:

  6. Pega Hrnjak 6/8 Technology improvements in 10 years as a consequence of refrigerant competition 5 5 R134a R744 driving (900 rpm) (2000 rpm) idling COP COP 0 0 25oC 35oC 25oC 35oC then now then now then now then now Improvement of efficiency for each system over 10 years at any condition is greater than the difference in system efficiency at any given time. >>

  7. Pega Hrnjak 7/8 Some realized improvements : 1. Internal HX (result: IHX in R134a MAC systems) Feb 22, 2006 DENSO Develops Unique Double-pipe Internal Heat Exchanger for Front Car Air Conditioning Systems: New pipe increases cooling performance by up to 12 percent 2. Evaporator and the control (result: microchannel evaporators for R134a). 3. CO2 comp efficiency is high. (result: R134a Cp w/o suction valve) 4. Work recovery devices: expanders/ejectors (result: first R134a ejector systems in Prius) May 20, 2009 KARIYA, Japan DENSO Corp. said this week it has developed the world s first passenger vehicle air conditioning system that uses ejector technology. The ejector, which is a small refrigerant injector, contributes to an overall reduction in power consumption. The system will be installed on the new Prius, introduced by Toyota this month.

  8. Pega Hrnjak 8/8 Consequently All improvements made for R134a initiated by CO2 were lately applied to R1234yf Additional competition or demands may push new frontiers New high glide options are potentially more cost effective but require further modification of the cycle and HXs to overcome challenging drop-in replacement

  9. Pega Hrnjak 9/8 Current R134a replacement may not be the winner yet R134a is already in phase out process with R1234yf Maybe more costly CO2 performs in a/c mode better at lower temperatures and in more compact systems R1234yf easier at higher ambient temperatures In the case of strengthening the importance of electric vehicles, CO2 gains the ground because no refrigerant comes close R445A also better than R1234yf in heat pumping

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