Understanding Tracer Studies and Disinfection in Water Treatment

Tracer studies play a crucial role in determining hydraulic efficiencies and disinfectant exposure times in water treatment processes. This presentation by Guy Schott covers the purpose of tracer studies, water age distribution, disinfection exposure time, CT disinfection, log inactivation, and more. Learn about the importance of reactor configuration, delivered dose to pathogens, log inactivation parameters, and how tracer studies help in optimizing water treatment processes.

• Water Treatment
• Tracer Studies
• Disinfection
• Hydraulic Efficiency
• Log Inactivation

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1. Tracer Studies Tracer Studies And Disinfection Guy Schott, P.E. Presented to AWWA Sacramento, CA March 27, 2019 ( ) ( ) ( ) ( ) 2 N 1 - 1 - 1 = + + .... + + C / C t/ t/ / FACT(2) t/ / FACT N 1 - exp - t/ N o

2. Learning Objectives 1. 2. 3. 4. 5. 6. 7. 8. 9. Purpose of a tracer study Water age distribution Disinfection exposure time CT disinfection (pathogen delivered dose) Log inactivation Baffling Factor (BF) Tracer test preparation Hydraulic efficiencies for different reactors Discussion

3. To determine the hydraulic or disinfectant exposure time of water through one or more reactors. Purpose of a Tracer Study Performed by the addition of a nonreactive chemical (tracer, marker).

4. 40% 60% of water age is 100 min or more 10% 90% of water age is 62 min or more

5. Based on the time it takes for 10% of the total water entering a reactor to be the first to exit the reactor. Determined via tracer study. Disinfection Exposure Time (t10)

6. Related to: Reactor configuration (inlet/outlet, baffles, L:W) Water Depth Working volume Flow rate Temperature gradient Hydraulic mixing Disinfectant Exposure Time

7. Cl2 Cl2 Cl2 Delivered Dose, Ct Cl2 Cl2 C is the disinfectant residual (mg/L) t is the disinfectant exposure or contact time (minutes) Delivered Dose to Pathogen (Ct) C x t= mg/L * min, delivered dose

8. Giardia cyst log inactivation is based on the Delivered Dose, Ct and associated pH Disinfectant residual Temperature Viruslog inactivation is based on the Delivered Dose, Ct and associated Disinfectant residual Temperature Disinfection Log Inactivation Parameters are looked up in EPA Ct tables to determine the log inactivation.

9. Generated from Tracer Study: t10= disinfectant exposure time HRT= hydraulic residence time = Volume/flow Baffling Factor (BF) = t10 / HRT 0 < BF< 1 BF is applied to the disinfection contact basin s operational HRT to determine contact time (t10, minutes). Calculated daily treatment plant disinfectant exposure time: t10_cal = BF x HRT Baffling Factor (BF)

10. Tracer Test Preparation 1. Reactor Process to Evaluate 2. Tracer methods 3. Tracer material 4. Tracer dosage 5. Test flows and reactor operating level 6. Test duration 7. Chemical feed pump 8. Sample locations 9. Sample frequency 10. Communication between parties involved

11. 1. Tracer Methods Step-Dose Curve Slug-Dose Curve 1.0 2.0 0.9 1.8 0.8 1.6 TRACER CONCENTRATION 0.7 1.4 0.6 1.2 C/Co 0.5 1.0 0.4 0.8 0.3 0.6 0.2 0.4 0.1 0.2 0.0 0.0 0.0 0.3 0.6 0.9 1.2 1.5 1.8 2.1 2.4 2.7 3.0 0.0 0.3 0.6 0.9 1.2 1.5 t/HRT 1.8 2.1 2.4 2.7 3.0 t/HRT Adding the entire amount of tracer at the beginning of test. A continuous tracer feed added throughout test.

12. Step-Dose Method A continuous tracer feed added throughout test. Slug-Dose Method Adding the entire amount of tracer at the beginning of test. Tracer Test Methods Tracer Q1 Cl2 Cl2 Q2 ti .. Tracer Chlorine Contact Basin

13. Model Step-Dose Curve Step-Dose Curve 1.0 0.9 0.8 0.7 0.6 C/CO 0.5 0.4 0.3 0.2 0.1 0.0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 t/HRT

14. Model Slug-Dose Curve Slug-Dose Curve 2.0 1.8 Tracer Concentration 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 t/HRT

15. Actual Slug-Dose Curve Slug-Dose Curve 2.0 1.8 Tracer Concentration 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8 3.0 t/HRT

16. Fluoride (F) Liquid (H2SiF6 Hydrofluorosilicic Acid) Dry (NaF) 15 gal NaF mix solution : 1 gal H2SiF6 Lithium Chloride (Li) Others (NaCl, CaCl2), dry or liquid 2. Tracer Material Tracer should be non-reactive

17. Step-Dose Fluoride: 2 to 4.0 mg/L as F Lithium: 0.5 mg/L Chloride/Na/Ca: Dependent on background constituents and any secondary standards 3. Dosage

18. Slug-Dose Test How Much Tracer to Add Calculated Dispersion Concentration in Basin Tracer Study Peak Concentration (estimated) t10/HRT (BF) 0.24 1.35 1.0 1. 2. Estimate BF Calculate amount of tracer mass needed for associated dispersion concentration. For lower or higher peak concentration, apply factor to dispersion concentration. 0.34 1.23 1.0 0.42 1.12 1.0 3. 0.51 0.95 1.0 0.61 0.76 1.0 0.70 0.58 1.0 .

19. One Test: Normal operating flow and clearwell level. Two Tests: Summer/winter flows and clearwell levels. Three Tests: High/mid/low flows and normal operating clearwell levels. 4A. Test Flows and Operating Level

20. Baffle tanks Higher flow, results in greater mixing (>Reynolds number & BF) At a given flow, increase tank volume (<Reynolds number & BF) Non-baffled tanks - Less predicable Temperature gradient can result in less mixing (<BF), greater short-circuiting. At a given flow, increase/decrease in tank volume (? Increase/decrease in BF) 4B. Test Flows and Operating Level

21. May vary from < 1 HRT to 4 HRT (site specific & predicted BF) 5A. Test Duration For full tracer recovery (slug-dose) and steady-state tracer (step-dose) 2.5 - 4 HRT duration

22. Modified the Step-Dose method Test is completed in less than 1 HRT Measurements of tracer inlet and outlet Inlet measurements: Flow into 5-gallon bucket over several minutes to ensure average applied tracer dosage is measured. Take sample out of bucket. Dump bucket and start over with next sample Average inlet sample results to determine applied dosage Outlet measurements: Sample duration < HRT 5B. Test Duration - When HRT is very long

23. Modified Step-Dose Method Clearwell Inlet Sampling Outlet Sampling Tracer All sampling is conducted to 1 x HRT or less

24. Actual Modified Step-Dose Test Curve Step-Dose Curve 0.16 0.14 0.12 0.10 C/Co 0.08 0.06 0.04 0.02 0.00 0.00 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24 0.27 0.30 0.33 0.36 0.39 0.42 0.45 0.48 0.51 0.54 t/HRT

25. Select chemical feed pump capacity based on plant flow and mL/min dosage range. Before tracer test, prime and test feed pump to ensure it works and stays on during duration of test. For slug-dose test, may be appropriate to temporarily shut down treatment plant for 2-5 minutes to inject tracer material and then start plant (site-specific). 6. Chemical Feed Pump

26. Sample distribution frequency is depended on baffling factor resolution goal around critical sampling region. Example: Goal e.g., measure to the nearest 0.02 baffling factor (BF). 1. HRT = 150 minutes Sample Frequency Critical Region 0.02 HRT = 0.02 150 min = 3 minutes Critical region is the area under curve where t10 occurs for a Step-Dose curve. 7. Sample Frequency

27. Reactor outlet Modified Step-Dose, inlet/outlet Use 5 gallon bucket for inlet sampling to obtain average inlet tracer dosage Take sample out of bucket Dump bucket and start over 8. Sample Locations

28. Plant personnel Regulatory agency Firm doing the tracer study By phone, email and/or written report 9. Communications

29. Variable outlet flow Modified step-dose method Take cumulative treated water volume (V10, gallons) from time zero (to) to t10 Divide cumulative volume (V10) by average working volume (V10/V) = BF When flows are not at steady-state BF= V10/V from tracer test (based on volume) V10: The volume of water that has exited the reactor from to to t10 when 10% of the tracer mass has exited the reactor. V: Average operating Clearwell volume of water during tracer test from to to t10.

30. Reactors Chlorine Contactors Top View BF (0.05-0.2) BF (0.3-0.4), L:W = 12 Circular Tanks BF (0.4-0.45), L:W = 16 BF (0.6-0.7), L:W = 52 Rectangular Tanks, Serpentine Flow BF is depended on reactor design, volume, water depth, flow and temperature gradient L:W is the total travel length of water divided by channel width or pipe diameter.

31. Determining L:W ratio Inlet Length is longest flow path (red line). Width is the average channel width for each flow path. Outlet

32. Determining L:W ratio Inlet Length is longest flow path (red line). Width is the average channel width for each flow path. Outlet

33. Length-to-Width Ratios vs. t10/HRT Baffled Tanks 1.0 0.9 0.8 0.7 0.6 t10/HRT 0.5 0.4 0.3 0.2 0.1 0.0 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 L/W AWWARF - Rectangular Clearwells SWRCB - Rectangular Clearwells SWRCB - Rectangular & Circular Clearwells SWRCB - Circular Clearwells

34. Contact Guy Schott, P.E. State Water Resources Control Board Division of Drinking Water Santa Rosa, CA For Tracer Study Database and/or Results: https://www.waterboards.ca.gov/drinking_ water/programs/districts/mendocino_distri ct.html Guy.Schott@waterboards.ca.gov 707-576-2732