Topic: Molecular Shape

Topic: Molecular Shape
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Explore the relationship between Lewis structures and molecular shapes, with a focus on factors influencing molecular geometry such as electron pairs and atoms around the central atom. Utilize VSEPR theory to predict shapes based on electron-pair repulsion. Understand how different atom arrangements result in linear, bent, trigonal planar, pyramidal, and tetrahedral molecular shapes.

  • Molecular Shape
  • Lewis Structure
  • VSEPR Theory
  • Electron Pairs
  • Atom Arrangements

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  1. Topic: Molecular Shape Do Now: Draw Lewis Dot Diagram for the following two compounds 1. CH2F2 2. CaO [ Ca ]+2

  2. Use the Lewis Structure Lewis structure is 2-D, but can help figure out 3-D shape H O H

  3. REMINDER:Bonding Capacity Atom Lewis Structure # Unpaired Electrons Bonding Capacity . H H .. 1 1 F, Cl, Br, I F: .. . 1 1 C, Si C ... 4 4 N, P N ... 3 3 O, S O: 2 2 Ne, Ar, Kr :Ne: 0 0

  4. Molecular Shape Determined by overlap of orbitals Shape determined by two factors: 1. # e- groups (pairs) around the central atom pay close attention to the free electron pairs 2. total # atoms bonded to central atom Free electron pairs Central Atom

  5. VSEPR (A model used to predict the shape of individual molecules based on the extent of electron-pair electrostatic repulsion) VSEPR= Valence shell electron pair repulsion: Basically free electrons will repel one another causing the molecule to bend

  6. 2 atoms (no central atom) Always linear Examples H2 O2 N2 HCl

  7. 3 atoms Can be linear or bent Must look at central atom If free electrons, then will be bent Central atom Free electrons so bent Central atom No free electrons so linear

  8. 4 atoms that form triangles Look at central atom No free electrons = trigonal planar - Free electrons = trigonal pyramidal

  9. 4-Atom Molecules: Planar = no real central atom, no free electrons either

  10. 5 atom molecules Always tetrahedral Examples CCl4 CH4 CH2I2

  11. Summary of Molecular Shapes Start with Lewis Structure! Look at total number of atoms Look at # of atoms bonded to central atom Look at free pair(s) of electrons around central atom

  12. Nonpolar Symmetrical Molecules Nonpolar

  13. Asymmetric Molecules Polar Bent & trigonal pyramidal are always polar

  14. Lets try a few Name the SHAPE and POLARITY

  15. BENT POLAR

  16. Trigonal Planar POLAR

  17. Tetrahedral POLAR

  18. Trigonal Pyramidal POLAR

  19. linear POLAR

  20. linear POLAR

  21. bent POLAR

  22. tetrahedral NONPOLAR

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