Terrestrial Planets and Core Dynamics

Terrestrial planets,
 the core situation
Core fractions
 
Rotation periods and magnetic fields:
 
58 days
very weak
 
243 days
extremely weak
 
24 hr
strong
 
30 days
very weak
 
25 hr
extr. weak
 
5.3 hr
Current geodynamos
Core-mantle interaction
 
early Hadean to present 
Outstanding questions
Outer core electrical and thermal conductivity
 
Indications of very high conductivity  
 
 
 "problems" with:
            
- the geodynamo (difficult to sustain)
            - age and size of the inner core
   
Stagnant layer of light buoyant melt near the CMB
Additional outer core heat sources?
Radioactivity: K, but possibly also U
  
U partitions to sulphide melt
 under very reducing conditions
        (corresponding to enstatite chondrites and to Mercury)
   
Sulphide can merge into the core metal
 
Exsolution of MgO from the core metal at CMB:
 
exothermic process 
 
(MgO incorporation in bm and fp) 
 
- requires MgO incorporation in the core at very high T during MO-stage
 - counteracted by dissolution of FeO from bm and fp
 
Selected references
Pozzo et al. (2012, Nature)
Helffrich & Kaneshima (2010, Nature)
Wohlers & Wood (2015, Nature)
Wahl & Militzer (2015, EPSL)
 
Ediacaran Period
 
Bono et al. 2019, Nat. Geosci.
”Mantle is the master  -  core is the slave”
       (Dave Stevenson, Caltech)
 
The 
rheology
 of the solid mantle 
imposes
 the
   convective and thermal regime of the core
Metals: Fe, Pt, Au, Ag, Cu
FCC
BCC
HCP
CCP
Pt, Au, Ag, Cu
, 
Cubic close-packed
Hexagonal close-packed
Face-centred cubic
Mg, Zn, Cd
CN: 12
CN: 8
Closest packing
Coord. number: 12
CN: 12
-Fe,
kamacite, ferrite
Body-centred cubic
-Fe, taennite
Li & Fei (2003,
Treat. Geochem)
Outermost
core
Fe
: 
melting curves and
       solid phase relations
 - challenging experiments
 - still large uncertainties
Dubrovinski et al.
   (2007, Science)
 
Belonoshko et al. 2017, Nat Geosci
bcc-Fe in the inner core
Tateno et al. (2010, Sci.)
- hcp-Fe in the inner core
- only 5100 K at 329 GPa (OC-IC-boundary)
- must assume a low-T geotherm
BUT:
 This is not specifically a melting study
Two electronic structure computational studies
 
(Stixrude 2012, Belonoshko et al. 2017)   
 
Probability density of atoms.
Central atom shown as a
small red sphere.
Fe
: 
melting curves and
       solid phase relations
 - challenging experiments
 - still large uncertainties
Is the inner core HP-bcc??  Probably not
Experimental melting of Fe
at core conditions
Anzellini et al. 2013, Science
Bohler (1993, Nature) 
-Fe
-Fe
Melting detected by:
1. Diffuse scattering and loss of XRD-peaks
     (in-situ, synchrotron-based XRD)
2. Temperature plateau
3. Volume plateau
Anzellini et al.
   2013, Sci.
Anzellini et al.
   2013, Sci.
Melting of Fe
  Anzellini et al.
  2013, Science
- Change/loss of XRD-peaks
- Diffuse scattering
 
T- and V plateaus
Melting of Fe: resistance heating
  Sinmyo et al. 2019, EPSL
 
Anzellini et al. 2013
 
Williams et al. 1987
 
Bohler et
 al. 1993
Lunar core structure
Weber et al. (2011, Science)
 
 Eutectic
composition
GPa    wt%
  
p
   Fe   S
   0    69   31
   3    74   26
  10    80  20
  14    82  18
  23    84  16
  40    88  12
System Fe-S
Stewart et al. (2007, Science)
Mars: 
a 
"snowing"
 core?
Mars’ core
100% liquid or 
constantly ”snowing”
Eutectic composition  
  1 bar:   29 wt% S
  3 GPa:  24 
10 GPa:  20
14 GPa:  18
23 GPa:  17
40 GPa:  13 wt% S
 
Chen et al. (2008, GRL)
 
Liquidi, Fe-S alloys with 1-12 wt% S
Mercury: also snowing core (?)
 
M a r s
FeO
mantle
 - core fraction
Trønnes et al. 2019,
    Tectonophysics
 
MESSENGER mission:
New and partly 
surprising
 results from Mercury
 
McCubbin et al.
(2012, GRL)
 
MESSENGER
:  MErcury Surface, Space
  ENvironment, GEochemistry and Ranging
 
High S
, in addition to 
low
 FeO
 
→ very reduced condition during accretion
       
(conditions similar to enstatite chondrite formation)
 
Enstatite chondrite minerals like 
oldhamite
 (CaS), 
niningerite
 (MgS) and
djerfisherite
 (alkali sulphide) are likely
Experimentally determined S-solubility in silicate melt
 
10
 
100
 
S-solubility wt%
 
1
 
0.1
 
-5 to -3
McCubbin et al.
     (2012, GRL)
Very low f
O
2
 
(O-content)
High Fe
0
-content, Si partitions to the metal
S-anions replace O in the silicate fraction
Moderate to high f
O
2
 
(O-content)
Stabilises FeS-rich sulphides
Chalcophile elements (incl. S) partition to metal
 
0.16
 
0.60
log f
O2
 
(
IW)
  =
  2 
*
 log (a
FeO
/a
Fe
)
Terrestrial planets
: core and mantle compositions
Observations, explanations
-
 Solar nebula zoning with increasing f
O
2
 outwards:
      
 Me →Ve → Ea → Ma → Vesta
-
 Moon’s 
tiny core
 and 
higher FeO
mantle
 (12%) than Venus-Earth (6-8%)
   
- Moon accreted mainly from 
Theia 
(+Earth) 
mantle debris
   - minor core core segregation at 
oxidising
 conditions at the post-GI stage
Trønnes et al. 2019,
    Tectonophysics
Core compositions
Inner planets
: Me-Ve-Ea
Reduced: 
IW < 
2:  
Si-rich
 cores. 
Ve and esp. Ea: also 
O
 
Outer bodies
: Mo-Ma-Vesta and the 
Fe-meteorites
Oxidised: 
IW > 
2:  
S-dominated
 cores
Trønnes et al. 2019,
    Tectonophysics
System Fe-FeO-FeS
, 1 bar -16 GPa
    with Fe/Ni=9 (right panels)
System Fe-FeO
, 1 bar, 16 GPa
Kato & Ringwood, 1989, PCM
Trønnes et al. 2019,
    Tectonophysics
Why do FeS-blobs exsolve
   from the Fe-rich melt?
Trønnes et al. 2019,
    Tectonophysics
Mercury
- 
Extremely reduced
 - very large core fraction
- FeS exsolution near the CMB (5.7 GPa) is likely
- approach to 3-phase equilibrium (metal, sulphide and
          silicate melts) at the magma ocean stage
 
The 
very high Si
core
 and separate exsolved FeS(?)
in Mercury reflect a 
very low O-content and O/S-
ratio 
of the mantle and crust with minerals like
n
iningerite
, (Mg,Fe,Mn)S, and 
oldhamite
, CaS,
which are also present in enstatite chondrites.
Trønnes et al. 2019,
    Tectonophysics
Element partitioning between immiscible sulfide and silicate melts
Kiseeva & Wood (2013, 2015, EPSL)
Wohlers & Wood (2015, Nat; 2017, GCA)
Wood & Kiseeva (2015, Am. Mineral.)
Experiments
- 1.5 GPa, 1400 C,
- variable f
O
2
 / compositions
BSE-image
 
Partitioning dependant on
 f
S
2
 and 
f
O
2
:
ZnO + 0.5 S
2
  =  ZnS + 0.5 O
2
 silicate                                sulfide
 
K
1
 = (a
ZnS
sulf
 
*
 
f
O
2
0.5
) 
/
 (a
ZnO
sil
 
*
 
f
S
2
0.5
)
 
a
ZnS
sulf 
/ a
ZnO
sil
  
  
[Zn]
sulf
 
/
 [Zn]
sil
  = D
Zn
sulf/sil
                  
D
Zn
sulf/sil
 
= 
K'
1
 
*
 (
f
S
2
/
f
O
2
)
0.5
 
Fugacities of S and O are difficult to
quantify  -  therefore the equation:
ZnO + FeS  = FeO + ZnS
 silicate        sulfide        silicate       sulfide
 
Zn and other chalcophiles are trace elements in the
FeS-dominated sulfide melt
  
 
a
FeS
sulf  
≈ 1
  
and:
                  
log D
Zn
sulf/sil
  
=  
K'
2
 - log a
FeO
sil
Generally, for a trace element M with valency n:
 
log D
M
sulf/sil
  
constant 
 
- (n/2)
 * 
log[FeO]
sil
 
K
2
 
= (
a
ZnS
sulf
/
a
ZnO
sil
)
 
*
 
(a
FeO
sil
/
a
FeS
sulf
)
   D
Zn
sulf/sil
 
= 
K'
2
 
*
 
a
FeS
sulf
/
a
FeO
sil
 
Because divalent Ni and Cu are abundant in sulfide
melts and mix nearly ideally with Fe
2+
, we can apply a
correction to [FeO]
sil
 to 
modify the approximation of
a
FeS
sulf
  
≈ 1
 (above):
   [FeO]
sil
 (corrected)  =  [FeO]
sil
 
/
 [Fe/(Fe+Ni+Cu)]
sil
 
Kiseeva & Wood (2013, 2015, EPSL)
Wohlers & Wood (2015, Nature)
Wood & Kiseeva (2015, Am. Mineral.)
 
Experiments
- 1.5 GPa, 1400 C,
- variable f
O
2
 / compositions
Strongly reducing conditions
(corresp. to enstatite chond. and Mercury)
- D
U
 and D
LREE
 approach unity
- D
Nd
 > D
Sm
 
Implications for:
 
- radioactive core heating
 - superchondritic Sm/Nd-ratios
      in the mantle
 
 if Earth accreted significant
   Mercury-like material
   
(Wohlers & Wood, 2015, Nature)
 
Comparative geodynamics
The effect of volatiles on rheology
– the Earth-Venus dichotomy
Aphrodite
Terra
Ishtar Terra
Venus topography: from Magellan
      
(radar mapping – topography better known
                                       than for Earth’s oceans)
 
Uniform cratering density:
 global resurfacing at 0.5-1 Ga
    Relatively flat
     
(mostly within 0.5 km from mean radius,
        max range: +/- 6 km, Earth: +9 to -11 km)
         Broad semi-circular elevated areas:
          indicating plume tectonics in a high-
          viscosity mantle
Earth:
Bimodal topography
Stable plate tectonics
 
Venus:
Unimodal topography
Volcanic mega-events
and global resurfacing
0.5-1 Ga cycles (?)
 
Small dome structures
(d = 25 km)
 
Large dome structure
- corona (d = 300 km)
Plume-peripheral subduction
 (sagduction) on Venus
Topography
 comparisons: Earth-Venus
 
Earth
: South Sandwitch trench
 
Venus
: Latona Corona
 
Venus
: Artemis Corona
 
Earth
: Aleutian trench
 
 Sandwell and Schubert (1992, Science)
 
1800 km
 
700 km
 
Alta
Regio
 
Latona
Corona
 
Beta Regio
 
N
 
N
 
 Sandwell and Schubert (1992, Science)
Davaille et al. (2017, Nature Geosci.)
- aqueous colloidal dispersions of silica nanoparticles,
- dried from above (lithospheric stiffness)
- uniformely heated from below, 
creating plumes
Fluid tank experiments
  Davaille et al. (2017, Nature Geosci.)
 
Oblique overview
 
Cross sectional views
 
1. Domal uplift
 
2. Initial plume extusion
     and sagging
 
3. Further extrusion and
    asymmetric extrusion
 
- domal uplift with triple-juction rifts
- followed by plume extrusion (460°C surface T),
    lithospheric sagging and subuction
 
T
i
m
e
 
l
a
p
s
e
 
v
i
e
w
:
4
0
,
 
8
0
,
 
-
-
-
,
 
4
8
0
 
s
 
S
a
g
g
i
n
g
l
i
t
h
o
s
p
h
e
r
e
 
L
a
s
e
r
-
i
m
a
g
e
d
 
s
i
d
e
 
v
i
e
w
 
L
a
s
e
r
-
i
m
a
g
e
d
 
s
i
d
e
 
v
i
e
w
 
V
i
e
w
 
f
r
o
m
 
t
h
e
 
t
o
p
 
a
t
 
2
6
0
 
s
,
 
i
n
i
t
i
a
l
 
r
i
f
t
i
n
g
 
i
n
 
r
e
d
 
c
o
l
o
u
r
Magnified top view:
Boundary between subducting lithosphere and plume (corona)
Three types of deformation features
c
: trench-parallel tension fractures near the surface
s
: trench-normal striations
cp
 
(yellow regions)
: compressive folds in lower part of the
                              plate in areas of high-curvature trench
surface
bubbles
Hexagonal plume structures
 
(within the corona)
Small-scale 
downwelling
 develping under the 
  thickening new skin
 
What makes Earth special ?
 
(esp. in relation to Venus)
 
Size
  Venus is slightly smaller, insufficient pressure for post-perovskite
 
Heliocentric distance
  
sufficient for surface H
2
O condensation – contrary to Venus
  
H
2
O greatly reduces mineral strength and mantle viscocity
  facilitating plate tectonics and H-recycling to the deep mantle
Convective Urey ratio
Ur = 
H
m
 /
 (
Q
om
+Q
cm
)
 
      = 
H
m
 / 
(
S
c
+
S
m
+
H
m
)
 
      =  
11
 / 
(
11
+
16
+
11
)
  = 11/38 = 0.29
Bulk Earth Urey ratio
Ur = 
(
H
m
 + H
cc
) 
/
 (
Q
om
+Q
cm
)
 
     
 = 
19
/38 = 0.50
Earth
Similarities:                                 
Radioactive
 
Radius
 
Mass
 
Density
 
        heat prod.
 
  km
 
10
24 
kg
 
kg/m
3
 
              
TW
Earth
 
6370
 
5,97
 
4030
 
        11
Venus
 
6050
 
4,87
 
3950, 
lower p
      ?
 
Contrasts:
 
Viscocity
 
Surf. heat flow
 
 10
19
 Pa s
 
     TW
Earth
 
rel. high
 
    46
Venus
 
 
higher?
 
  
lower at
                                          steady state?
Sister planets Earth and Venus
 
Venus
Rotation period: 243 days 
(retrograde)
Geodynamo: very weak
Surface condition: 
480 C,  92 bar
Atmosphere:  97% CO
2 
  3% N
2
 
Earth
Rotation period: 1 day 
(prograde)
Geodynamo: strong
Surface condition
 
: 
15 C,  1 bar
Atmosphere:  78% N
2 
  21% O
2
   1% Ar
 
Venus
- Long periods with  heating
        shorter resurfacing episodes
- Plume(-sagduction) tectonics
 
Earth
- Stable mantle convection and
     internal heat flow
- Oceans and stable plate tectonics
Venus might have been Earth-like and habitable in the
Archean during the faint young Sun 
(70% at 4.5 Ga) 
period
Why so different atmospheres when the inventories of
  C, N, O and H was similar in the beginning ?
Where is Earth’s carbon corresponding to Venus’ 92 bar
  CO
2
-dominated atmosphere ?
 
Venus:
- No condensation of volanically degassed H
2
O
-
 Upper atmosphere photo-dissociation of H
2
O
-
 H
2
-escape
-
 Dry planet, no hydro- or cryosphere
Earth
:
- Oceans, precipitation of CaCO
3
-
 Photosynthesis 
→ O
2
, biomass and black shales
- Hydration of ocean floor
-
 Recycling of wet lithosphere with carbonaceous
    material and limestone by subduction
 
753 K
Earth
1 bar
:   78% N
2
   21% O
2
   1% Ar
Venus
92 bar !!
   
97% CO
2
   3% N
2
Venus
A volatile-free peridotite solidus applies
Earth
Melting, viscosity and a pronounced
lithosphere-asthenosphere division is
promoted by deep recycling of CO
2
and H
2
O   
 
LAB
 
LAB
 
LAB:
lithosphere-
asthenosphere
boundary
 
0.1 wt%
 
0.03 wt%
The Earth-Venus dichotomy shows:
 
- importance of H (H
2
O) og other volatiles (e.g. CO
2
)
     in planetary dynamics
 
- how a rel. small difference  in heliocentric difference can
     cause a large difference in planetary evolution
 
-
 how atmosphere and hydrosphere can be tied to internal
   mantle dynamics (on Earth, not on Venus)
In addition: Earth is larger than Venus
Very low 
 in the 
D"-zone of 
Earth with fast
   and 
efficient CMB flow and heat transfer
Pbm stabilization in Earth’s D"-zone, not in Venus
Slide Note
Embed
Share

Exploring the core-mantle interaction from the early Hadean period to present times reveals intriguing questions about the outer core's electrical conductivity, geodynamo sustainability, and inner core characteristics. Studies indicate challenges in maintaining the geodynamo, potential heat sources in the outer core, and the role of radioactivity in core composition. Researchers have suggested processes like exsolution of MgO and sulphide melt incorporation into the core metal. Understanding the metallic composition, melting curves of Fe, and solid phase relations offer valuable insights into the planetary cores' complex dynamics.

  • Terrestrial Planets
  • Core Dynamics
  • Geodynamo
  • Mantle
  • Core Composition

Uploaded on Apr 05, 2024 | 9 Views


Download Presentation

Please find below an Image/Link to download the presentation.

The content on the website is provided AS IS for your information and personal use only. It may not be sold, licensed, or shared on other websites without obtaining consent from the author. Download presentation by click this link. If you encounter any issues during the download, it is possible that the publisher has removed the file from their server.

E N D

Presentation Transcript


  1. Terrestrial planets, the core situation

  2. Current geodynamos Rotation periods and magnetic fields: Core fractions 58 days very weak 243 days extremely weak 24 hr strong 30 days very weak 5.3 hr 25 hr extr. weak

  3. Core-mantle interaction early Hadean to present Outstanding questions Outer core electrical and thermal conductivity Indications of very high conductivity "problems" with: - the geodynamo (difficult to sustain) - age and size of the inner core Stagnant layer of light buoyant melt near the CMB Additional outer core heat sources? Radioactivity: K, but possibly also U U partitions to sulphide melt under very reducing conditions (corresponding to enstatite chondrites and to Mercury) Sulphide can merge into the core metal Exsolution of MgO from the core metal at CMB: exothermic process (MgO incorporation in bm and fp) - requires MgO incorporation in the core at very high T during MO-stage - counteracted by dissolution of FeO from bm and fp Selected references Pozzo et al. (2012, Nature) Helffrich & Kaneshima (2010, Nature) Wohlers & Wood (2015, Nature) Wahl & Militzer (2015, EPSL)

  4. Bono et al. 2019, Nat. Geosci. Ediacaran Period

  5. The rheology of the solid mantle imposes the convective and thermal regime of the core Mantle is the master - core is the slave (Dave Stevenson, Caltech)

  6. Metals: Fe, Pt, Au, Ag, Cu Cubic close-packed CCP Face-centred cubic FCC Closest packing Coord. number: 12 CN: 12 g-Fe, taennite Pt, Au, Ag, Cu, Hexagonal close-packed HCP CN: 12 Mg, Zn, Cd Body-centred cubic BCC CN: 8 a-Fe, kamacite, ferrite

  7. Fe: melting curves and solid phase relations - challenging experiments - still large uncertainties Outermost core Outermost core Li & Fei (2003, Treat. Geochem)

  8. Fe: melting curves and solid phase relations - challenging experiments - still large uncertainties Is the inner core HP-bcc?? Probably not g a e Li & Fei (2003, Treat. Geoch.) Dubrovinski et al. (2007, Science) Tateno et al. (2010, Sci.) - hcp-Fe in the inner core - only 5100 K at 329 GPa (OC-IC-boundary) - must assume a low-T geotherm BUT: This is not specifically a melting study Two electronic structure computational studies (Stixrude 2012, Belonoshko et al. 2017) Stixrude (2012, PRL) Melt Belonoshko et al. 2017, Nat Geosci bcc-Fe in the inner core Probability density of atoms. Central atom shown as a small red sphere. OC: >4000 K g g e e 136 GPa CMB: a a

  9. Experimental melting of Fe at core conditions Anzellini et al. 2013, Science Anzellini et al. 2013, Sci. Melting detected by: 1. Diffuse scattering and loss of XRD-peaks (in-situ, synchrotron-based XRD) 2. Temperature plateau 3. Volume plateau e-Fe g-Fe Anzellini et al. 2013, Sci.

  10. Melting of Fe Anzellini et al. 2013, Science - Change/loss of XRD-peaks - Diffuse scattering T- and V plateaus

  11. Melting of Fe: resistance heating Sinmyo et al. 2019, EPSL

  12. Lunar core structure Weber et al. (2011, Science)

  13. System Fe-S Brett & Bell (1969, EPSL) Chen et al. (2008, GRL) Fe wt% 90 80 90 80 Stewart et al. (2007, Science) Eutectic composition GPa wt% p Fe S 0 69 31 3 74 26 10 80 20 14 82 18 23 84 16 40 88 12

  14. Stewart et al. (2007, Science) Mars: a "snowing" core? Eutectic composition 1 bar: 29 wt% S 3 GPa: 24 10 GPa: 20 14 GPa: 18 23 GPa: 17 40 GPa: 13 wt% S Mars core 100% liquid or constantly snowing

  15. Liquidi, Fe-S alloys with 1-12 wt% S Mercury: also snowing core (?) Chen et al. (2008, GRL)

  16. FeOmantle- core fraction Tr nnes et al. 2019, Tectonophysics

  17. MESSENGER mission: New and partly surprising results from Mercury MESSENGER: MErcury Surface, Space ENvironment, GEochemistry and Ranging High S, in addition to low FeO very reduced condition during accretion (conditions similar to enstatite chondrite formation) McCubbin et al. (2012, GRL) Enstatite chondrite minerals like oldhamite (CaS), niningerite (MgS) and djerfisherite (alkali sulphide) are likely

  18. Experimentally determined S-solubility in silicate melt 100 Inferred S-solubility in early Mercurian basalts: 1.5 4.0 wt% log 1.5 = 0.16 log 4.0 = 0.60 10 0.60 0.16 1 S-solubility wt% McCubbin et al. (2012, GRL) 0.1 -5 to -3 Very low fO2(O-content) High Fe0-content, Si partitions to the metal S-anions replace O in the silicate fraction Moderate to high fO2(O-content) Stabilises FeS-rich sulphides Chalcophile elements (incl. S) partition to metal

  19. Trnnes et al. 2019, Tectonophysics Terrestrial planets: core and mantle compositions log fO2(DIW) = 2 * log (aFeO/aFe) Observations, explanations - Solar nebula zoning with increasing fO2outwards: Me Ve Ea Ma Vesta - Moon s tiny core and higher FeOmantle(12%) than Venus-Earth (6-8%) - Moon accreted mainly from Theia (+Earth) mantle debris - minor core core segregation at oxidising conditions at the post-GI stage

  20. Core compositions Tr nnes et al. 2019, Tectonophysics Inner planets: Me-Ve-Ea Reduced: DIW < -2: Si-rich cores. Ve and esp. Ea: also O Outer bodies: Mo-Ma-Vesta and the Fe-meteorites Oxidised: DIW > -2: S-dominated cores

  21. Trnnes et al. 2019, Tectonophysics System Fe-FeO-FeS, 1 bar -16 GPa with Fe/Ni=9 (right panels) System Fe-FeO, 1 bar, 16 GPa Kato & Ringwood, 1989, PCM 3073 K ionic liquid 2773 K metallic liquid 2273 K 1773 K 2473 K metallic liquid ionic liquid 2273 K 2073 K 1873 K

  22. Trnnes et al. 2019, Tectonophysics Why do FeS-blobs exsolve from the Fe-rich melt? Immiscible FeS-drop. (troilite) Cape York (Agpalilik) iron meteorite (Slice at NHM, Univ. Oslo)

  23. Trnnes et al. 2019, Tectonophysics Mercury - Extremely reduced - very large core fraction - FeS exsolution near the CMB (5.7 GPa) is likely - approach to 3-phase equilibrium (metal, sulphide and silicate melts) at the magma ocean stage The very high Sicoreand separate exsolved FeS(?) in Mercury reflect a very low O-content and O/S- ratio of the mantle and crust with minerals like niningerite, (Mg,Fe,Mn)S, and oldhamite, CaS, which are also present in enstatite chondrites.

  24. Element partitioning between immiscible sulfide and silicate melts Kiseeva & Wood (2013, 2015, EPSL) Wohlers & Wood (2015, Nat; 2017, GCA) Wood & Kiseeva (2015, Am. Mineral.) Partitioning dependant on fS2and fO2: ZnO + 0.5 S2= ZnS + 0.5 O2 silicate sulfide K1= (aZnSsulf*fO20.5) / (aZnOsil*fS20.5) aZnSsulf / aZnOsil [Zn]sulf/ [Zn]sil= DZn DZn sulf/sil Experiments - 1.5 GPa, 1400 C, - variable fO2/ compositions sulf/sil= K'1* (fS2/fO2)0.5 Fugacities of S and O are difficult to quantify - therefore the equation: ZnO + FeS = FeO + ZnS silicate sulfide silicate sulfide K2= (aZnSsulf/aZnOsil)* (aFeOsil/aFeSsulf) DZn sulf/sil= K'2* aFeSsulf/aFeOsil Zn and other chalcophiles are trace elements in the FeS-dominated sulfide melt aFeSsulf 1 and: log DZn sulf/sil= K'2 - log aFeOsil Generally, for a trace element M with valency n: log DM sulf/sil constant - (n/2)* log[FeO]sil BSE-image Because divalent Ni and Cu are abundant in sulfide melts and mix nearly ideally with Fe2+, we can apply a correction to [FeO]silto modify the approximation of aFeSsulf 1 (above): [FeO]sil(corrected) = [FeO]sil/ [Fe/(Fe+Ni+Cu)]sil

  25. Kiseeva & Wood (2013, 2015, EPSL) Wohlers & Wood (2015, Nature) Wood & Kiseeva (2015, Am. Mineral.) Experiments - 1.5 GPa, 1400 C, - variable fO2/ compositions

  26. Strongly reducing conditions (corresp. to enstatite chond. and Mercury) - DUand DLREEapproach unity - DNd> DSm Implications for: - radioactive core heating - superchondritic Sm/Nd-ratios in the mantle if Earth accreted significant Mercury-like material (Wohlers & Wood, 2015, Nature)

  27. Comparative geodynamics The effect of volatiles on rheology the Earth-Venus dichotomy

  28. Venus topography: from Magellan (radar mapping topography better known than for Earth s oceans) Ishtar Terra Uniform cratering density: global resurfacing at 0.5-1 Ga Relatively flat (mostly within 0.5 km from mean radius, max range: +/- 6 km, Earth: +9 to -11 km) Broad semi-circular elevated areas: indicating plume tectonics in a high- viscosity mantle Aphrodite Terra

  29. Earth: Bimodal topography Stable plate tectonics Venus: Unimodal topography Volcanic mega-events and global resurfacing 0.5-1 Ga cycles (?)

  30. Large dome structure - corona (d = 300 km) Small dome structures (d = 25 km)

  31. Plume-peripheral subduction (sagduction) on Venus Topography comparisons: Earth-Venus Sandwell and Schubert (1992, Science) Venus: Latona Corona Earth: South Sandwitch trench Venus: Artemis Corona Earth: Aleutian trench

  32. Sandwell and Schubert (1992, Science) Beta Regio N Alta Regio N Latona Corona

  33. Davaille et al. (2017, Nature Geosci.) Artemis Corona, 2000-2400 km diameter Complex interior geology: intensely deformed linear, arcuate fracture zones, numerous volcanic flows, and "corona-like" features, c. Three rift segments, r, radiate outwards from the peripheral trench. Quetzalpetlatl Corona, 1500-2000 km diameter A roughly fractured arc, QC, appear radar bright (grey scale inset). Exterior rift branches, r, radiate outwards. BC: Boala Corona

  34. Fluid tank experiments Davaille et al. (2017, Nature Geosci.) View from the top at 260 s, initial rifting in red colour - aqueous colloidal dispersions of silica nanoparticles, - dried from above (lithospheric stiffness) - uniformely heated from below, creating plumes - domal uplift with triple-juction rifts - followed by plume extrusion (460 C surface T), lithospheric sagging and subuction Oblique overview Laser-imaged side view Sagging lithosphere Cross sectional views Laser-imaged side view 3. Further extrusion and asymmetric extrusion 1. Domal uplift 2. Initial plume extusion and sagging Time lapse view: 40, 80, ---, 480 s

  35. Magnified top view: Boundary between subducting lithosphere and plume (corona) Three types of deformation features c: trench-parallel tension fractures near the surface s: trench-normal striations cp (yellow regions): compressive folds in lower part of the plate in areas of high-curvature trench Hexagonal plume structures (within the corona) Small-scale downwelling develping under the thickening new skin surface bubbles

  36. What makes Earth special ? (esp. in relation to Venus) Size Venus is slightly smaller, insufficient pressure for post-perovskite Heliocentric distance sufficient for surface H2O condensation contrary to Venus H2O greatly reduces mineral strength and mantle viscocity facilitating plate tectonics and H-recycling to the deep mantle

  37. Earth Convective Urey ratio Ur = Hm/ (Qom+Qcm) = Hm/ (Sc+Sm+Hm) = 11 / (11+16+11) = 11/38 = 0.29 Bulk Earth Urey ratio Ur = (Hm+ Hcc) / (Qom+Qcm) = 19/38 = 0.50

  38. Sister planets Earth and Venus Similarities: Radioactive Radius Mass km 1024 kg Earth 6370 5,97 Venus 6050 4,87 Contrasts: Density kg/m3 4030 3950, lower p heat prod. TW 11 ? Viscocity 1019Pa s rel. high higher? Surf. heat flow TW 46 Earth Venus lower at steady state?

  39. Earth Rotation period: 1 day (prograde) Geodynamo: strong Surface condition : 15 C, 1 bar Atmosphere: 78% N2 21% O21% Ar Venus Rotation period: 243 days (retrograde) Geodynamo: very weak Surface condition: 480 C, 92 bar Atmosphere: 97% CO2 3% N2

  40. Venus - Long periods with heating shorter resurfacing episodes - Plume(-sagduction) tectonics Earth - Stable mantle convection and internal heat flow - Oceans and stable plate tectonics

  41. Venus might have been Earth-like and habitable in the Archean during the faint young Sun (70% at 4.5 Ga) period

  42. Why so different atmospheres when the inventories of C, N, O and H was similar in the beginning ? Where is Earth s carbon corresponding to Venus 92 bar CO2-dominated atmosphere ? 753 K Venus: - No condensation of volanically degassed H2O - Upper atmosphere photo-dissociation of H2O - H2-escape - Dry planet, no hydro- or cryosphere Earth: - Oceans, precipitation of CaCO3 - Photosynthesis O2, biomass and black shales - Hydration of ocean floor - Recycling of wet lithosphere with carbonaceous material and limestone by subduction

  43. Earth 1 bar: 78% N221% O21% Ar Venus 92 bar !! 97% CO23% N2

  44. Venus A volatile-free peridotite solidus applies Earth Melting, viscosity and a pronounced lithosphere-asthenosphere division is promoted by deep recycling of CO2 and H2O LAB LAB: lithosphere- asthenosphere boundary 0.03 wt% 0.1 wt% LAB

  45. The Earth-Venus dichotomy shows: - importance of H (H2O) og other volatiles (e.g. CO2) in planetary dynamics - how a rel. small difference in heliocentric difference can cause a large difference in planetary evolution - how atmosphere and hydrosphere can be tied to internal mantle dynamics (on Earth, not on Venus)

  46. In addition: Earth is larger than Venus Pbm stabilization in Earth s D"-zone, not in Venus Very low h h in the D"-zone of Earth with fast and efficient CMB flow and heat transfer

Related


More Related Content

giItT1WQy@!-/#giItT1WQy@!-/#giItT1WQy@!-/#giItT1WQy@!-/#giItT1WQy@!-/#giItT1WQy@!-/#