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N
N
2
2
O & THE MONTREAL PROTOCOL
O & THE MONTREAL PROTOCOL
Technical and Policy Issues
Technical and Policy Issues
David Kanter
PhD candidate
Princeton University
November 22
nd
, 2011
MOP 23, Bali, Indonesia
Outline
Breakdown of N
2
O emissions sources
Point vs. non-point sources
Global N
2
O emission trends
Why should Montreal Protocol (MP) take on N
2
O?
How can emissions be reduced?
Industry & stationary/mobile combustion
Agriculture
Behavioral changes
Technological opportunities
How can targets be developed and implemented?
Existing policies
Assessment Panels and the Multilateral Fund (MLF)
Conclusions & Next Steps
 
N
2
O emissions breakdown
Princeton University 
(2011) “Complements to Carbon”
 
Point sources
:
Industry (from nitric acid and
adipic acid production)
Stationary combustion (e.g. coal
power plants)
Wastewater treatment facilities
 
Non-point sources
:
Agriculture (synthetic fertilizer,
manure, legumes…)
Mobile combustion (transport)
Biomass burning
undefined
Global N
2
O Emission Trends
(
USEPA
, 2011
)
Why should MP take on N
2
O?
N
2
O now most abundant ODS in atmosphere,  with emissions
projected to increase (
Ravishankara et al.
 2009)
Current international tools for controlling N
2
O are weak
Little attention to N
2
O within Kyoto Protocol – CDM has focused solely
on industrial N
2
O emissions
Increasing calls to regulate non-CO
2
 climate forcers in non-UNFCCC
forums (
Molina et al. 
2009; HFC Amendments 2009-2011)
MP well-suited for N
2
O
Rising N
2
O emissions threaten MP’s continued success
Effective, well-respected assessment panels
Successful financial mechanism (MLF)
Binding (common and differentiated) commitments of all Parties
 
Why are N
2
O reduction opportunities different?
Much more publicly available information on N
2
O
reduction strategies
Industry associations acknowledge both environmental
impacts of N
2
O and effectiveness of reduction strategies
(e.g. International Fertilizer Industry Association (IFA) says
N
2
O emissions can be reduced by 25% using existing
practices and technologies – 
IFA
, 2009)
Leading companies already developing and marketing
abatement technologies (e.g. Yara International), in
addition to publicizing best practices.
N
2
O reductions have more environmental co-benefits
(ozone, climate, air, water)
How emissions can be reduced: Industry et al.
Nitric and adipic acid manufacturing
Nitric acid
:  
Catalytic reduction techniques, which reduce both N
2
O and
NO
x
 emissions by over 90% (
SEI
 2010). 20% of US plants have N
2
O
abatement technology installed (
USEPA
, 2006)
Adipic acid
: 
Catalytic decomposition and thermal destruction techniques,
which reduce N
2
O emissions by approx. 95% (
USEPA
 2011). 90% of US
plants have N
2
O abatement technology installed (
USEPA
, 2006)
Transport
Next generation catalytic converters – reduce N
2
O 
and
 NO
x
 emissions
(EPA/DoT regulations)
Stationary combustion
Improved combustion technologies (e.g. pressurized fluidized bed
combustion) and catalytic reduction techniques (
CARB
)
How emissions can be reduced:
Agriculture
Behavioral practices
Fertilizer best management practices (
Robertson &
Vitousek
 2009):
Watershed management
Crop residue recycling
Precision & split fertilizer application
Legume cultivation/cover crop
Manure management
4Rs: Right product, right rate, right time, right place (IFA)
How emissions can be reduced:
Agriculture (Cont.)
Technological solutions:
Nitrification inhibitors
Additives to traditional fertilizers that delay production of nitrate (NO
3
)
Reduce N
2
O emissions by approx. 40% (
Akiyama et al. 
2009).
Used on 10% of US maize cropland (
Mosier et al
., 2004)
Controlled-release fertilizers 
Coating or chemical modification of fertilizer, which slows the rate of
nutrient release.
Reduce N
2
O emissions by approx. 35% (
Akiyama et al., 
2009)
 Used on <1% of US cropland due to cost (
Mosier et al. 
2004)
Other
 Breeding and genetic engineering of crops to increase N
use efficiency
How can reductions be implemented?
Industrial emission reductions:
Easiest to implement and could be addressed before agriculture.
Technological solutions available for all facilities (of which there are a
limited number).
Agricultural N
2
O emissions:
Begin with most cost effective reductions. N fertilizer is essential to crop
production, but ~50% lost to the environment. Improvements would
reduce costs and N pollution.
Goal is to use existing N fertilizers more efficiently, as well as encourage
adoption of new fertilizer technologies.
Due to tight coupling of N cycle, care should be taken not to
exacerbate other forms of N pollution while reducing N
2
O
(
Galloway et al., 
2003).
Existing N Policies
N
2
O:
EU Emissions Trading Scheme (ETS)
 
– Credit for N
2
O emissions reductions from
nitric acid plants will be issued starting in 2013.
Alberta (Canada) Quantification Protocol for Agricultural N
2
O Emissions
Reductions
 
– Issues credits for on-farm reductions of N
2
O emissions and fuel
use associated with management of fertilizer, manure and crop residues.
Kyoto Protocol 
- Handful of CDM projects to reduce industrial N
2
O emissions.
US EPA/Dept. of Transportation
 
Cap on tailpipe N
2
O emissions of 0.010g per
mile.
UK Climate Change Act
N
2
O covered under a general GHG reduction target
Australia Carbon Tax 
N
2
O to be covered
Reactive N (indirect impact on N
2
O):
EU
 -Nitrates Directive
USA
 - Safe Drinking Water Act, Clean Water Act, Clean Air Act
International
 - Convention on Long Range Transport of Air Pollution
Assessment Panels and MLF
Assessment panels:
Logical next step given N
2
O’s threat to ozone layer would be to create
new sub-panel within Technology and Economics Assessment
Panel(Environmental Effects Panel & Scientific Assessment Panel
already cover N
2
O – see 
SAP
, 2010).
Experts exist on both environmental impacts of N
2
O and technical
solutions across the globe in both the public and private sector.
Multilateral Fund (MLF):
Clear incremental costs and available technologies for industrial
emissions abatement
Similar strategy to methyl bromide for agricultural N
2
O emissions
would be suitable - a mix of technology transfer and training, technical
assistance and information dissemination projects.
Conclusions and next steps
Conclusions:
N
2
O’s ozone depleting properties, weak international controls, as
well as MP’s institutional structure all favor inclusion of N
2
O in the
MP.
Significant N
2
O emission reductions are possible across most
sectors
Emissions reductions are already being implemented by a suite of
policies, which should be harnessed by MP, but global controls
necessary
Next steps:
TEAP (or TEAP-like) report (and/or a Special Report in conjunction
with the IPCC) on N
2
O reduction opportunities.
Industry workshop (under TEAP auspices) on N
2
O reduction
opportunities.
References
Akiyama et al. (2010) “Evaluation of effectiveness of enhanced-efficiency fertilizers as
mitigation options for N
2
O and NO emissions from agricultural soils: meta-analysis”, 
Global
Change Biology
, 16:1837-1846
California Air Resources Board “Options for N
2
O emission reductions related to stationary
combustion” (B.2.2)
Galloway et al. (2003) “The nitrogen cascade”, 
Bioscience
, 53, 341-356
IFA (2009) “Fertilizers, climate change, and enhanced agricultural productivity sustainably”
Molina et al. (2009) “Reducing abrupt climate change risk using the Montreal Protocol and
other regulatory actions to complement cuts in CO2 emissions”, 
PNAS
Mosier et al. (2004) “Agriculture and the Nitrogen Cycle” (SCOPE)
SEI (2010) “Industrial N2O projects under the CDM: The case of nitric acid production”, SEI
Working Paper  WP-US-1007
Robertson G.P., Vitousek P. (2009) “Nitrogen in Agriculture: Balancing the Cost of an Essential
Resource”, 
Annu. Rev. Environ. Resour
., 34:97-125
USEPA (2006) “Global mitigation of non-CO
2 
greenhouse gases”
USEPA (2011) “DRAFT: Global Anthropogenic Non-CO2 Greenhouse Gas Emissions: 1990 –
2030”
Acknowledgements & Questions
Thanks to Ravishankara and Pete Grabiel for their support
and participation.
Thanks to Professors Denise Mauzerall, Bill Moomaw (Tufts),
Bob Keohane & Michael Oppenheimer for their on-going
intellectual support.
Thanks to Siebel Energy Challenge, Princeton Institute for
International & Regional Studies (PIIRS), and Princeton
Science Technology, and Environmental Policy (STEP) program
for funding this trip.
Questions?
Slide Note

We’ve heard how rising N2O emissions are threatening the recovery of the stratospheric ozone layer, as well as some of the legal pathways the MP could pursue in order to take on N2O. I’m now going to go through the major technical and policy issues as I see them for moving N2O under the MP

None of the views presented here represent the views of Princeton University, IGSD or NOAA.

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  1. November 22nd, 2011 MOP 23, Bali, Indonesia N2O & THE MONTREAL PROTOCOL Technical and Policy Issues David Kanter PhD candidate Princeton University

  2. Outline Breakdown of N2O emissions sources Point vs. non-point sources Global N2O emission trends Why should Montreal Protocol (MP) take on N2O? How can emissions be reduced? Industry & stationary/mobile combustion Agriculture Behavioral changes Technological opportunities How can targets be developed and implemented? Existing policies Assessment Panels and the Multilateral Fund (MLF) Conclusions & Next Steps

  3. N2O emissions breakdown Point sources: Industry (from nitric acid and adipic acid production) Stationary combustion (e.g. coal power plants) Wastewater treatment facilities Non-point sources: Agriculture (synthetic fertilizer, manure, legumes ) Mobile combustion (transport) Biomass burning Princeton University (2011) Complements to Carbon

  4. Global N2O Emission Trends (USEPA, 2011)

  5. Why should MP take on N2O? N2O now most abundant ODS in atmosphere, with emissions projected to increase (Ravishankara et al. 2009) Current international tools for controlling N2O are weak Little attention to N2O within Kyoto Protocol CDM has focused solely on industrial N2O emissions Increasing calls to regulate non-CO2 climate forcers in non-UNFCCC forums (Molina et al. 2009; HFC Amendments 2009-2011) MP well-suited for N2O Rising N2O emissions threaten MP s continued success Effective, well-respected assessment panels Successful financial mechanism (MLF) Binding (common and differentiated) commitments of all Parties

  6. Why are N2O reduction opportunities different? Much more publicly available information on N2O reduction strategies Industry associations acknowledge both environmental impacts of N2O and effectiveness of reduction strategies (e.g. International Fertilizer Industry Association (IFA) says N2O emissions can be reduced by 25% using existing practices and technologies IFA, 2009) Leading companies already developing and marketing abatement technologies (e.g. Yara International), in addition to publicizing best practices. N2O reductions have more environmental co-benefits (ozone, climate, air, water)

  7. How emissions can be reduced: Industry et al. Nitric and adipic acid manufacturing Nitric acid: Catalytic reduction techniques, which reduce both N2O and NOx emissions by over 90% (SEI 2010). 20% of US plants have N2O abatement technology installed (USEPA, 2006) Adipic acid: Catalytic decomposition and thermal destruction techniques, which reduce N2O emissions by approx. 95% (USEPA 2011). 90% of US plants have N2O abatement technology installed (USEPA, 2006) Transport Next generation catalytic converters reduce N2O and NOx emissions (EPA/DoT regulations) Stationary combustion Improved combustion technologies (e.g. pressurized fluidized bed combustion) and catalytic reduction techniques (CARB)

  8. How emissions can be reduced: Agriculture Behavioral practices Fertilizer best management practices (Robertson & Vitousek 2009): Watershed management Crop residue recycling Precision & split fertilizer application Legume cultivation/cover crop Manure management 4Rs: Right product, right rate, right time, right place (IFA)

  9. How emissions can be reduced: Agriculture (Cont.) Technological solutions: Nitrification inhibitors Additives to traditional fertilizers that delay production of nitrate (NO3) Reduce N2O emissions by approx. 40% (Akiyama et al. 2009). Used on 10% of US maize cropland (Mosier et al., 2004) Controlled-release fertilizers Coating or chemical modification of fertilizer, which slows the rate of nutrient release. Reduce N2O emissions by approx. 35% (Akiyama et al., 2009) Used on <1% of US cropland due to cost (Mosier et al. 2004) Other Breeding and genetic engineering of crops to increase N use efficiency

  10. How can reductions be implemented? Industrial emission reductions: Easiest to implement and could be addressed before agriculture. Technological solutions available for all facilities (of which there are a limited number). Agricultural N2O emissions: Begin with most cost effective reductions. N fertilizer is essential to crop production, but ~50% lost to the environment. Improvements would reduce costs and N pollution. Goal is to use existing N fertilizers more efficiently, as well as encourage adoption of new fertilizer technologies. Due to tight coupling of N cycle, care should be taken not to exacerbate other forms of N pollution while reducing N2O (Galloway et al., 2003).

  11. Existing N Policies N2O: EU Emissions Trading Scheme (ETS) Credit for N2O emissions reductions from nitric acid plants will be issued starting in 2013. Alberta (Canada) Quantification Protocol for Agricultural N2O Emissions Reductions Issues credits for on-farm reductions of N2O emissions and fuel use associated with management of fertilizer, manure and crop residues. Kyoto Protocol - Handful of CDM projects to reduce industrial N2O emissions. US EPA/Dept. of Transportation Cap on tailpipe N2O emissions of 0.010g per mile. UK Climate Change Act N2O covered under a general GHG reduction target Australia Carbon Tax N2O to be covered Reactive N (indirect impact on N2O): EU -Nitrates Directive USA - Safe Drinking Water Act, Clean Water Act, Clean Air Act International - Convention on Long Range Transport of Air Pollution

  12. Assessment Panels and MLF Assessment panels: Logical next step given N2O s threat to ozone layer would be to create new sub-panel within Technology and Economics Assessment Panel(Environmental Effects Panel & Scientific Assessment Panel already cover N2O see SAP, 2010). Experts exist on both environmental impacts of N2O and technical solutions across the globe in both the public and private sector. Multilateral Fund (MLF): Clear incremental costs and available technologies for industrial emissions abatement Similar strategy to methyl bromide for agricultural N2O emissions would be suitable - a mix of technology transfer and training, technical assistance and information dissemination projects.

  13. Conclusions and next steps Conclusions: N2O s ozone depleting properties, weak international controls, as well as MP s institutional structure all favor inclusion of N2O in the MP. Significant N2O emission reductions are possible across most sectors Emissions reductions are already being implemented by a suite of policies, which should be harnessed by MP, but global controls necessary Next steps: TEAP (or TEAP-like) report (and/or a Special Report in conjunction with the IPCC) on N2O reduction opportunities. Industry workshop (under TEAP auspices) on N2O reduction opportunities.

  14. References Akiyama et al. (2010) Evaluation of effectiveness of enhanced-efficiency fertilizers as mitigation options for N2O and NO emissions from agricultural soils: meta-analysis , Global Change Biology, 16:1837-1846 California Air Resources Board Options for N2O emission reductions related to stationary combustion (B.2.2) Galloway et al. (2003) The nitrogen cascade , Bioscience, 53, 341-356 IFA (2009) Fertilizers, climate change, and enhanced agricultural productivity sustainably Molina et al. (2009) Reducing abrupt climate change risk using the Montreal Protocol and other regulatory actions to complement cuts in CO2 emissions , PNAS Mosier et al. (2004) Agriculture and the Nitrogen Cycle (SCOPE) SEI (2010) Industrial N2O projects under the CDM: The case of nitric acid production , SEI Working Paper WP-US-1007 Robertson G.P., Vitousek P. (2009) Nitrogen in Agriculture: Balancing the Cost of an Essential Resource , Annu. Rev. Environ. Resour., 34:97-125 USEPA (2006) Global mitigation of non-CO2 greenhouse gases USEPA (2011) DRAFT: Global Anthropogenic Non-CO2 Greenhouse Gas Emissions: 1990 2030

  15. Acknowledgements & Questions Thanks to Ravishankara and Pete Grabiel for their support and participation. Thanks to Professors Denise Mauzerall, Bill Moomaw (Tufts), Bob Keohane & Michael Oppenheimer for their on-going intellectual support. Thanks to Siebel Energy Challenge, Princeton Institute for International & Regional Studies (PIIRS), and Princeton Science Technology, and Environmental Policy (STEP) program for funding this trip. Questions?

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