Metric System and Sig Figs in Chemistry

 
Chemistry – Sept 9, 2019
 
P3 Challenge –
1. How many sig figs do each of these contain?
A)   3.80 x 10
8
      B)   4700  
 
C)   0.001090
2. Perform the following operations and round to the proper number of sigfigs.
A)  9.866 m  x  13.5 m
B)  9.866 m – 13.5 m
 
 
Pick up 3 handouts regarding the lab for next class.
 
Objectives and Agenda
 
Objectives
To Use the Metric System
Agenda
SI Units
The Metric System
3 Unit Conversion methods
The Ladder
Powers of 10
Dimensionalysis
 
 
SI (metric) System
 
BASE UNITS (all defined relative to the 3
standards above)
meter
 for length
kilogram
 for mass (note: not the
gram)
second
 for time
ampere for electric current
kelvin
 for temperature
candela for luminous intensity
mole 
for the amount of substance
 
DERIVED UNITS
liter
 for volume  (1 mL = 1 cm
3
)
PREFIXES (Memorize these 5 for convenience)
Allows units to be a convenient size for
observations
The mole concept
 
The 
mole
 allows us to connect the macroscopic and atomic scales.
(An instance of the CCC Scale, Proportion and Quantity)
A mole is a unit like dozen or ream.
A mole simply counts some number of items.
So…how many is a mole?
1 mole = 6.022 x 10
23
     There are 6.022 x 10
23
 items in one mole of
anything.
 
 
Complete Set of Prefixes
Converting Method 1 –  Move decimal
 
Imagine the list of prefixes as a 
ladder
. For 
each step on the ladder 
from
your starting unit to your target unit, you will move your 
decimal one place
.
If you move to a 
larger unit
, 
UP
 the ladder, the 
number
 will get 
smaller
.
Move decimal to 
left
.
If you move to a 
smaller unit
, 
DOWN
 the ladder, the 
number 
will get 
larger
.
Move decimal to 
right
.
Smaller unit needs bigger number. Bigger unit needs smaller number.
Ex:    945 mL  
  L    (Small unit to larger unit, move decimal left 3)
Ex:    3.5 kg  
   mg (Large unit to smaller unit, move decimal right…)
Ex:  
 
25.32 m
2
 
  cm
2 
 
(Convert both dimensions)
Converting method 2 – Powers of 10
 
Each of the 
prefix labels 
can be considered a variable that has the 
value of its defined power of
10
.
You may replace 10
3
 with k.
You may replace k with 10
3
.
Convenient to use if values are in 
scientific notation
Ex: 
3.4 x 10
2
 nm 
   m
 
( n means 10
-9
)   3.4 x 10
2
 x 10
-9
 m = 3.4 x 10
-7
 m
Ex: 4.78 x 10
-2
 m 
 cm    (Target needs 10
-2
)   4.78 x 
10
-2
 m = 4.78 
c
m
Ex: 3.58 x 10
-4 
cm  
  
μ
m  (Target needs 10
-6
 m) 3.58 x 10
-4
 x 10
-2 
m= 3.58 x 
10
-6
 m = 3.58 
μ
m
Trick: If you don’t have the powers of 10 you need, you can multiply by a special form of 1
Ex:  (10
-3
 x 10
3
) = 10
0
 = 1
 
 or  Ex: (10
-6
 x 10
6
) = 10
0
 = 1
Ex:  6.13 x 10
-5
 mg 
 kg  (Target needs 10
3
) 6.13 x 10
-5
 x 10
-3
 x (
10
3
 x 10
-3
) g = 6.13 x 10
-11
 
k
g
Metric Conversions Practice
 
Ex: 452 mm   
   m
Ex: 6.78 x 10
-7
 km  
 m
Ex: 5.7 x 10
-9
 L  
  
μ
L
Ex: 2.3 L 
 mL
Ex:  0.0000213 km 
 mm
Ex: 1.05 x 10
5
 km
2
  
  m
2
If you’ve got scientific
notation, the power of 10
method is going to work best.
If you’ve got standard
notation, the ladder moving
decimals method is going to
work best.
Conversion Method 3 – Dimensionalysis
 
1.
Write the measured value with its unit. (
Given)
2.
Draw the multiplication symbol and a division line.
3.
Copy the unit to the bottom of the conversion factor to cancel.
 
“Times sign, draw a line, copy the unit”
4.
Write the 
target unit 
on the top of the conversion factor.
5.
Find an 
equivalence
 using these two units and complete the
conversion factor.
6.
Multiply and cancel units. (
Multiply by tops, divide by bottoms
)
7.
Report value with the 
target unit
. (
Use correct sigfigs
)
Conversion Method 3 – Dimensionalysis
 
Also called the factor label method
Ex: How many individual eggs are there in 22 dozens of eggs?
 
22 dozen
 
dozen
 
eggs
 
1
 
12
 
= 264 eggs
 
Valid process because all conversion factors = 1.
 
Meter Stick Equivalences
 
Three equivalences are used often in conversion factors
They are called the meter stick equivalences because they all relate to the
meter stick
Easy to visualize and remember.
 
 
 
 
Also works for other base units: 1000 mL = 1 L
Conversion Method 3 – Dimensionalysis
Practice with Conversion factors
 
“Times sign, draw a line, copy the unit”
Ex:  73 cm 
 m
Ex: 3.55 L  mL
Ex:  0.359 g  mg
Ex:  5.8 
μ
m  mm
Think 5.8 
μ
m  m  mm   (use two conversion factors)
 
 
Penny Density Lab Overview
 
In 1983, the composition of pennies was changed. How did this affect their
density?
Purpose: To measure the density of pennies before 1983, and after 1983.
How?
Both the mass and volume of “new” pennies and “old” pennies 
are
measured. Mass using an electronic scale (2 decimal places) and volume
using a graduated cylinder (1 decimal place) and 
water displacement
.
Data collected 
for 1, 2, 3, 4, 5, 6 and 7 pennies
.
Data 
GRAPHED 
 such that the 
slope
 of the 
graph
 is the 
density
. (2 graphs)
Formal Lab Report 
writing.
 
Exit Slip - Homework
 
Order the following metric units from largest to smallest:
μm , cm, km, m, mm, nm, Mm
 
What’s Due?  (Pending assignments to complete.)
Complete the Metric Conversions Worksheet (due Wednesday)
Read Penny Lab document and General Lab Report Format, Complete the
Prelab (due Wednesday before starting the lab)
What’s Next?  (How to prepare for the next day)
Read p12-16  Factor Label Method
 
Metric WS Ans
 
1. a) 1.20 cm
b) 0.2485 L
c) 0.101 kg
d) 0.035 m
2
e) 970 m
f) 1,580,000  mg
g) 0.000183 km
h) 6200 
μ
s
 
2. a) 5.48 x 10
-3
 nm
b) 13 L
c) 3.17 x 10
-2
 m
2
d) 1.92 x 10
6
 mm
2
e) 7.79 
μ
m
 
3. 
a) 6.51 m
b) 7,835 g
 
Metric WS Ans
 
4. a) 2.77 m
b) 
620 m
c) 3,857,000 mg
d) 3.40 x 10
2
 L 
 
or  340. g
e) 2.3 x 10
-2
 L   or  0.023 L
f) 
1.275 x 10
4 
km   or  12,750 km
g) 0.078 mL
h) 3.4 x 10
2 
 ms or  340 ms
 
i) 3 x 10
2
 Mm  or 300 Mm
j) 3.6 
μ
L
k) 0.856 kg
l) 
8.06 x 10
-6
 mm
m) 81.05 m
2
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Explore the fundamentals of the metric system, significant figures, and unit conversions in the context of chemistry. Gain insights into the mole concept, prefixes, and methods for handling calculations with appropriate precision. Get ready to tackle questions and operations related to sig figs, measurements, and lab tasks.

  • Chemistry
  • Metric System
  • Significant Figures
  • Unit Conversions
  • Mole Concept

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  1. Chemistry Sept 9, 2019 P3 Challenge 1. How many sig figs do each of these contain? B) 4700 A) 3.80 x 108 C) 0.001090 2. Perform the following operations and round to the proper number of sigfigs. A) 9.866 m x 13.5 m B) 9.866 m 13.5 m Pick up 3 handouts regarding the lab for next class.

  2. Objectives and Agenda Objectives To Use the Metric System Agenda SI Units The Metric System 3 Unit Conversion methods The Ladder Powers of 10 Dimensionalysis

  3. SI (metric) System BASE UNITS (all defined relative to the 3 standards above) DERIVED UNITS liter for volume (1 mL = 1 cm3) meter for length PREFIXES (Memorize these 5 for convenience) kilogram for mass (note: not the gram) Allows units to be a convenient size for observations second for time Prefix Kilo- Deci- Centi- Milli- Micro- Abbreviation Power of 10 k d c m ampere for electric current 103 10-1 10-2 10-3 10-6 kelvin for temperature candela for luminous intensity mole for the amount of substance

  4. The mole concept The mole allows us to connect the macroscopic and atomic scales. (An instance of the CCC Scale, Proportion and Quantity) A mole is a unit like dozen or ream. A mole simply counts some number of items. So how many is a mole? 1 mole = 6.022 x 1023 anything. There are 6.022 x 1023items in one mole of

  5. Complete Set of Prefixes Prefix Meaning Example Symbo l T G M k d c m n p tera giga mega- kilo- deci- centi- milli- micro- nano- pico- 1 000 000 000 000 or 1012 1 000 000 000 or 109 1 000 000 or 106 1 000 or 103 0.1 or 10-1 0.01 or 10-2 0.001 or 10-3 0.000 001 or 10-6 0.000 000 001 or 10-9 0.000 000 000 001 or 10-12 1 Ts = 1 000 000 000 000 s = 1012s 1 Gs = 1 000 000 000 s = 109s 1 Ms = 1 000 000 s = 106s 1 ks = 1000 s = 103s 1 ds = 0.1 s = 10-1s 1 cs = 0.01 s = 10-2s 1 ms = 0.001 s = 10-3s 1 s = 0.000 001 s = 10-6s 1 ns = 0.000 000 001 s = 10-9s 1 ps = 0.000 000 000 001 s = 10-12s

  6. Converting Method 1 Move decimal T 12 Imagine the list of prefixes as a ladder. For each step on the ladder from your starting unit to your target unit, you will move your decimal one place. G 9 If you move to a larger unit, UP the ladder, the number will get smaller. Move decimal to left. M 6 If you move to a smaller unit, DOWN the ladder, the number will get larger. Move decimal to right. k 3 Smaller unit needs bigger number. Bigger unit needs smaller number. L (Small unit to larger unit, move decimal left 3) mg (Large unit to smaller unit, move decimal right ) cm2 (Convert both dimensions) Base d c m 0 -1 Ex: 945 mL -2 -3 Ex: 3.5 kg Ex: 25.32 m2 -6 n -9

  7. Converting method 2 Powers of 10 Each of the prefix labels can be considered a variable that has the value of its defined power of 10. You may replace 103 with k. You may replace k with 103. Convenient to use if values are in scientific notation m ( n means 10-9) 3.4 x 102 x 10-9 m = 3.4 x 10-7 m cm (Target needs 10-2) 4.78 x 10-2 m = 4.78 cm m (Target needs 10-6 m) 3.58 x 10-4 x 10-2 m= 3.58 x 10-6 m = 3.58 m Ex: 3.4 x 102 nm Ex: 4.78 x 10-2 m Ex: 3.58 x 10-4 cm Trick: If you don t have the powers of 10 you need, you can multiply by a special form of 1 Ex: (10-3 x 103) = 100 = 1 or Ex: (10-6 x 106) = 100 = 1 Ex: 6.13 x 10-5 mg kg (Target needs 103) 6.13 x 10-5 x 10-3 x (103 x 10-3) g = 6.13 x 10-11 kg

  8. Metric Conversions Practice Ex: 452 mm Ex: 6.78 x 10-7 km Ex: 5.7 x 10-9 L Ex: 2.3 L mL Ex: 0.0000213 km Ex: 1.05 x 105 km2 m If you ve got scientific notation, the power of 10 method is going to work best. m L If you ve got standard notation, the ladder moving decimals method is going to work best. mm m2

  9. Conversion Method 3 Dimensionalysis Write the measured value with its unit. (Given) Draw the multiplication symbol and a division line. Copy the unit to the bottom of the conversion factor to cancel. Times sign, draw a line, copy the unit Write the target unit on the top of the conversion factor. Find an equivalence using these two units and complete the conversion factor. Multiply and cancel units. (Multiply by tops, divide by bottoms) Report value with the target unit. (Use correct sigfigs) 1. 2. 3. 4. 5. 6. 7.

  10. Conversion Method 3 Dimensionalysis Also called the factor label method Ex: How many individual eggs are there in 22 dozens of eggs? 12 eggs 22 dozen = 264 eggs dozen 1 Valid process because all conversion factors = 1.

  11. Meter Stick Equivalences Three equivalences are used often in conversion factors They are called the meter stick equivalences because they all relate to the meter stick Easy to visualize and remember. 1 m = 100 cm 1 m = 1000 mm 1000 m = 1 km Also works for other base units: 1000 mL = 1 L

  12. Conversion Method 3 Dimensionalysis Any prefix definition can be turned into two equivalence statements: Milli- m 10-3 1 mm = 10-3 m and 1 m = 103 mm = 1000 mm Any equivalence statement can be turned into a fraction that equals 1 mm ?? ?m m or ?? ?m m Multiply any unit by a conversion factor such that units cancel. mm ? m m Ex: ? mm ???m mm m or ???? m mm m ? m m ? m mm mor ? m m Ex: 56 m x ???? mm = 56,000 mm = 5.6 x 104 mm

  13. Practice with Conversion factors Times sign, draw a line, copy the unit Ex: 73 cm m Ex: 3.55 L mL Ex: 0.359 g mg Ex: 5.8 m mm Think 5.8 m m mm (use two conversion factors)

  14. Penny Density Lab Overview In 1983, the composition of pennies was changed. How did this affect their density? Purpose: To measure the density of pennies before 1983, and after 1983. How? Both the mass and volume of new pennies and old pennies are measured. Mass using an electronic scale (2 decimal places) and volume using a graduated cylinder (1 decimal place) and water displacement. Data collected for 1, 2, 3, 4, 5, 6 and 7 pennies. Data GRAPHED such that the slope of the graph is the density. (2 graphs) Formal Lab Report writing.

  15. Exit Slip - Homework Order the following metric units from largest to smallest: m , cm, km, m, mm, nm, Mm What s Due? (Pending assignments to complete.) Complete the Metric Conversions Worksheet (due Wednesday) Read Penny Lab document and General Lab Report Format, Complete the Prelab (due Wednesday before starting the lab) What s Next? (How to prepare for the next day) Read p12-16 Factor Label Method

  16. Metric WS Ans 1. a) 1.20 cm 2. a) 5.48 x 10-3 nm b) 0.2485 L b) 13 L c) 0.101 kg c) 3.17 x 10-2 m2 d) 0.035 m2 d) 1.92 x 106 mm2 e) 970 m e) 7.79 m f) 1,580,000 mg g) 0.000183 km 3. a) 6.51 m h) 6200 s b) 7,835 g

  17. Metric WS Ans 4. a) 2.77 m i) 3 x 102 Mm or 300 Mm b) 620 m j) 3.6 L c) 3,857,000 mg k) 0.856 kg d) 3.40 x 102 L or 340. g l) 8.06 x 10-6 mm e) 2.3 x 10-2 L or 0.023 L m) 81.05 m2 f) 1.275 x 104 km or 12,750 km g) 0.078 mL h) 3.4 x 102 ms or 340 ms

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