Ceramic Fourth Class: Glass and Ceramic Fabrication and Processing Overview

 
CERAMIC- FOURTH
 
CLASS
 
F
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f
 
G
l
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s
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s
 
a
n
d
 
G
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C
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a
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Soda
 
and
 
lime
 
are
 
added
 
to
 
a
 
glass
batch 
in the form of soda 
ash
(Na2CO3) and 
limestone 
(CaCO3).
During 
heating, these 
two
 
ingredients
decompose to give 
off 
carbon 
dioxide
(CO2), 
the resulting products
 
being
soda
 
and
 
lime.
 
Compute
 
the
 
weight
 
of
soda ash and 
limestone that 
must
 
be
 
CERAMIC- FOURTH
 
CLASS
 
added
 
to
 
125
 
lbm
 
of
 
quartz
 
(SiO2)
 
to
 
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yield  a
 
glass
 
of
 
composition  
78
 
wt%
 
SiO2, 17 wt% Na2O, and 5 wt%
 
CaO.
What is 
the 
distinction 
between 
glass
transition temperature 
and 
melting
temperature?
Compare the 
temperatures 
at which
soda– lime, borosilicate, 
96% silica,
and 
fused 
silica may be
 
annealed.
 
CERAMIC- FOURTH
 
CLASS
Compare 
the softening points 
for
 
96%
silic
a
,
 
bo
rosilicate,
 
a
n
d
 
s
o
d
a
–l
i
me
glasses.
Explain 
why residual 
thermal
 
stresses
are 
introduced 
into a glass piece
when it is
 
cooled.
Are 
thermal stresses introduced 
upon
heating? 
Why 
or 
why
 
not?
 
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CERAMIC- FOURTH
 
CLASS
Borosili
c
ate
 
gla
s
ses
 
a
n
d
 
f
us
e
d
 
silica
are 
resistant 
to 
thermal shock. 
Why
 
is
this
 
so?
In your 
own words, 
briefly 
describe
what 
happens as 
a glass piece 
is
thermally
 
tempered.
Glass 
pieces 
may 
also 
be
strengthened 
by chemical tempering.
With this procedure, the 
glass
 
surface
is put in a state of compression 
by
exchanging 
some 
of the 
cations
 
near
 
4 
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e
 
CERAMIC- FOURTH
 
CLASS
 
the 
surface 
with other cations
 
having
 
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e
 
a
 
larger
 
diameter.
 
Suggest
 
one
 
type
 
of
c
a
ti
o
n
 
t
h
at,
 
by
 
r
e
pla
c
i
ng
 
N
a
+,
 
will
induce 
chemical tempering 
in 
a
 
soda–
 
Processing
 
of
 
Clay
 
lime
 
glass.
Fabricat
i
o
n
 
and
Products
 
Cite the 
two desirable
 
characteristics
of clay 
minerals 
relative to 
fabrication
processes.
 
CERAMIC- FOURTH
 
CLASS
From a molecular perspective,
 
briefly
explain 
the 
mechanism 
by which 
clay
min
e
r
als
 
become
 
h
y
d
r
o
plast
i
c
 
w
hen
 
water 
is
 
added.
What are the 
three 
main 
components
of a whiteware 
ceramic such as
porcelain?
What 
role 
does each 
component play
in 
the 
forming 
and 
firing
 
procedures?
 
6 
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CERAMIC- FOURTH
 
CLASS
Why
 
is
 
it
 
so
 
important
 
to 
control
 
the
rate of drying of a 
ceramic 
body 
that
has
 
been
 
hydropl
a
stic
a
l
l
y
 
fo
r
med
 
or
 
slip
 cast?
Cite 
three 
factors that 
influence 
the
rate of 
drying, and explain how each
affects 
the
 
rate.
Cite one 
reason 
why drying
 
shrinkage
is greater for slip 
cast 
or 
hydroplastic
products that have 
smaller 
clay
particles.
 
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CERAMIC- FOURTH
 
CLASS
 
Name 
three 
factors that 
influence
 
the
degree to 
which vitrification occurs 
in
claybased ceramic
 
wares.
Explain how 
density, firing
 
distortion,
strength, corrosion resistance, and
thermal 
conductivity 
are 
affected 
by 
the
extent of
 vitrification.
 
8 
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CERAMIC- FOURTH
 
CLASS
 
P
o
w
d
e
r
 
P
r
e
s
s
i
n
g
 
9 
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Some
 
ceramic
 
materials
 
are
fabricated
 
by
 
h
ot
 
isostatic
 
p
ressing.
Cite
 
so
m
e
 
of
 
the
 
limitat
i
o
n
s
 
and
diff
i
c
u
lt
ie
s
 
assoc
i
ated
 
wi
t
h
 
this
technique.
D
E
S
I
G
N
 
P
R
O
B
L
E
M
 
modern
 
kitchen
 
Some
 
o
f
 
o
u
r
cookware
 
is
 
m
a
de
 
of
 
ceramic
 
materia
l
s.
 
CERAMIC- FOURTH
 
CLASS
Li
s
t
 
at
 
least
 
three
 
imp
o
r
t
ant
characteristics required 
of a material
to be 
used 
for 
this
 
application.
Make a comparison of three
 
ceramic
materials as 
to their 
relative 
properties
and, in addition, 
to
 
cost.
On 
the 
basis of this 
comparison,
select 
the material most suitable for
the
 
cookware.
 
Written by 
Assist. 
Lec 
Athil S.
 
Ibrahim
 
A
l
l
 
t
h
e
 
b
e
s
t
 
10 
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The Ceramic Fourth Class covers topics such as glass and glass ceramic fabrication, composition calculations, thermal properties of different glasses, introduction of thermal stresses in glass pieces, resistance to thermal shock, thermal tempering processes, clay mineral characteristics, whiteware ceramics components, and factors influencing the rate of drying in ceramics.

  • Ceramic
  • Glass fabrication
  • Thermal properties
  • Clay minerals
  • Whiteware ceramics

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  1. CERAMIC- FOURTH CLASS Fabrication and Processing of Glasses and Glass Ceramics Soda and lime are added to a glass batch in the form of soda ash (Na2CO3) and limestone (CaCO3). During heating, these two ingredients decompose to give off carbon dioxide (CO2), the resulting products being soda and lime. Compute the weight of soda ash and limestone that must be 1| P a g e

  2. CERAMIC- FOURTH CLASS added to 125 lbm of quartz (SiO2) to yield a glass of composition 78 wt% SiO2, 17 wt% Na2O, and 5 wt%CaO. What is the distinction between glass transition temperature and melting temperature? Compare the temperatures at which soda lime, borosilicate, 96% silica, and fused silica may be annealed. 2| P a g e

  3. CERAMIC- FOURTH CLASS Compare the softening points for96% silica, borosilicate, and soda lime glasses. Explain why residual thermal stresses are introduced into a glass piece when it is cooled. Are thermal stresses introduced upon heating? Why or why not? 3| P a g e

  4. CERAMIC- FOURTH CLASS Borosilicate glasses and fused silica are resistant to thermal shock. Why is this so? In your own words, briefly describe what happens as a glass piece is thermally tempered. Glass pieces may also be strengthened by chemical tempering. With this procedure, the glass surface is put in a state of compression by exchanging some of the cations near 4| P a g e

  5. CERAMIC- FOURTH CLASS the surface with other cations having a larger diameter.Suggestone type of cation that, by replacing Na+, will induce chemical tempering in asoda lime glass. Fabrication and Processing of Clay Products Cite the two desirable characteristics of clay minerals relative to fabrication processes. 5| P a g e

  6. CERAMIC- FOURTH CLASS From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added. What are the three main components of a whiteware ceramic such as porcelain? What role does each component play in the forming and firing procedures? 6| P a g e

  7. CERAMIC- FOURTH CLASS Why is it so important to control the rate of drying of a ceramic body that has been hydroplastically formed or slip cast? Cite three factors that influence the rate of drying, and explain how each affects the rate. Cite one reason why drying shrinkage is greater for slip cast or hydroplastic products that have smaller clay particles. 7| P a g e

  8. CERAMIC- FOURTH CLASS Name three factors that influence the degree to which vitrification occurs in claybased ceramic wares. Explain how density, firing distortion, strength, corrosion resistance, and thermal conductivity are affected by the extent of vitrification. 8| P a g e

  9. CERAMIC- FOURTH CLASS Powder Pressing Some ceramic materials are fabricated by hot isostatic pressing. Cite some of the limitations and difficulties associated with this technique. DESIGN PROBLEM Some of our modern kitchen made of ceramic cookware is materials. 9| P a g e

  10. CERAMIC- FOURTH CLASS List at least three important characteristics required of a material to be used for this application. Make a comparison of three ceramic materials as to their relative properties and, in addition, to cost. On the basis of this comparison, select the material most suitable for the cookware. Written by Assist. Lec Athil S. Ibrahim All the best 10| P a g e

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